Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density...

32
54 Chapter 3 What You’ll Learn You will distinguish between physical and chemical properties. You will classify matter by composition: element, com- pound, or mixture. You will identify observable characteristics of chemical reactions. You will explain the funda- mental law of conservation of mass. Why It’s Important You are completely sur- rounded by matter. To better understand this matter—how it affects you, how you affect it, and how it can be manipu- lated for the benefit of soci- ety—you need to build a basic understanding of the types and properties of matter. Matter—Properties and Changes CHAPTER 3 Visit the Chemistry Web site at chemistrymc.com to find links about matter, properties, and changes. Chemistry is the study of matter and its properties. Every aspect of these divers’ environment, under water and on land, is some form of matter.

Transcript of Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density...

Page 1: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

54 Chapter 3

What Yoursquoll LearnYou will distinguishbetween physical andchemical properties

You will classify matter bycomposition element com-pound or mixture

You will identify observablecharacteristics of chemicalreactions

You will explain the funda-mental law of conservationof mass

Why Itrsquos ImportantYou are completely sur-rounded by matter To betterunderstand this mattermdashhowit affects you how you affectit and how it can be manipu-lated for the benefit of soci-etymdashyou need to build a basicunderstanding of the typesand properties of matter

MattermdashProperties andChanges

CHAPTER 3

Visit the Chemistry Web site atchemistrymccom to find linksabout matter properties andchanges

Chemistry is the study of matterand its properties Every aspect ofthese diversrsquo environment underwater and on land is some formof matter

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31 Properties of Matter 55

DISCOVERY LAB

Materials

large test tubetest-tube holder or rack10 mL HClzinc metalwood splintmatch or burner

Observing Chemical Change

Consider the metal objects that are part of the everyday world Amailbox for example stands outside day in and day out without

seeming to change Under what conditions does metal exhibit chem-ical change

Safety Precautions

Procedure

1 Place a piece of zinc metal in a large test tube

2 Add approximately 10 mL of 3M hydrochloric acid (HCl) to the testtube Record your observationsCAUTION HCI causes burns and hazardous fumes

3 When the zinc and HCl have reacted for approximately 1 minbring a lighted glowing wood splint to the mouth of the testtube CAUTION Be sure the test tube is facing away from yourface when the splint is brought near Again record yourobservations

Analysis

What may have caused the dynamic reaction you observed in step 3Did you expect this reaction Explain

Always wear eye goggles gloves and anapron when experimenting with chemicalsUse caution when handling an open flame

Objectivesbull Identify the characteristics

of a substance

bull Distinguish between physi-cal and chemical properties

bull Differentiate among thephysical states of matter

Vocabularysubstancephysical propertyextensive propertyintensive propertychemical propertystates of mattersolidliquidgasvapor

Section 31 Properties of Matter

Imagine yourself scuba diving through a complex biological ecosystem suchas a coral reef What kinds of things fill your imagination Regardless of whatyou envision there is only one answermdashyou see matter The diversity of mat-ter in the world and in the universe is astounding From pepperoni pizzas tosupernovas itrsquos all matter If we are to understand this diversity we must startwith a way of organizing and describing matter

SubstancesRecall from Chapter 1 that chemistry is the study of matter and matter isanything that has mass and takes up space Everything around you is mat-ter including things such as air and microbes which you cannot see Forexample table salt is a simple type of matter that you are probably familiarwith Table salt has a unique and unchanging chemical composition It isalways 100 sodium chloride and its composition does not change from onesample to another Matter that has a uniform and unchanging compositionis called a substance also known as a pure substance Table salt is a sub-stance Another example of a pure substance is water Water is always com-posed of hydrogen and oxygen Seawater on the other hand is not asubstance because samples taken from different locations will probably have

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differing compositions That is they will contain differing amounts of watersalts and other dissolved substances Given this definition what other puresubstances are you familiar with Substances are important much of yourchemistry course will be focused on the processes by which substances arechanged into different substances

Physical Properties of MatterYou are used to identifying objects by their propertiesmdashtheir characteristicsand behavior For example you can easily identify a pencil in your backpackbecause you recognize its shape color weight or some other property Thesecharacteristics are all physical properties of the pencil A physical propertyis a characteristic that can be observed or measured without changing the sam-plersquos composition Physical properties describe pure substances too Becausesubstances have uniform and unchanging compositions they have consistentand unchanging physical properties as well Density color odor taste hard-ness melting point and boiling point are common physical properties thatscientists record as identifying characteristics of a substance Sodium chlo-ride forms solid white crystals at room temperature all having the sameunique salty taste Table 3-1 lists several common substances and their phys-ical properties

Extensive and intensive properties Physical properties can be furtherdescribed as being one of two types Extensive properties are dependent uponthe amount of substance present For example mass which depends on theamount of substance there is is an extensive property Length and volume arealso extensive properties Density on the other hand is an example of an inten-

sive property of matter Intensive properties are independentof the amount of substance present For example density of asubstance (at constant temperature and pressure) is the sameno matter how much substance is present

A substance can often be identified by its intensive prop-erties In some cases a single intensive property is uniqueenough for identification During the California gold rushminers relied on goldrsquos characteristic density (19 gcm3) toseparate valuable gold-containing flakes from riverbed sandThe process used by the miners is shown in Figure 3-1Another intensive property of gold is its distinctiveappearance Unfortunately miners often learned that iden-tification of gold based on appearance alone was mislead-ing Figure 3-2 shows a nugget of the relatively worthless

56 Chapter 3 MattermdashProperties and Changes

Figure 3-1

Miners relied on the physicalproperty of density to distin-guish gold (19 gcm3) from theworthless minerals in their sluicepans The density of pyrite aworthless mineral often mis-taken for gold is 5 gcm3

Physical Properties of Common Substances

State Melting Boiling DensitySubstance Color at 25degC point (degC) point (degC) (gcm3)

Oxygen Colorless Gas 218 ndash183 00014

Mercury Silver Liquid ndash39 357 135

Water Colorless Liquid 0 100 100

Sucrose White Solid 185 Decomposes 159

Sodium White Solid 801 1413 217chloride

Table 3-1

Science WriterDo you get excited about newsin science and technology Doyou like to explain informationin a way that others find inter-esting and understandableThen consider a career as a science writer

Science writers keep up-to-dateon what is happening in theworld of science and translatethat news so nonscientists canunderstand it These writerswork for newspapers maga-zines scientific publicationstelevision stations and Internetnews services Lots of curiosityas well as a degree in a scienceandor journalism is essential

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mineral pyrite often called ldquofoolrsquos goldrdquo which looks very similar to actualgold nuggets Such errors in identification based on the intensive property ofappearance fooled many miners into falsely thinking they had struck it rich

Chemical Properties of MatterSome properties of a substance are not obvious unless the substance haschanged composition as a result of its contact with other substances or theapplication of thermal or electrical energy The ability of a substance to com-bine with or change into one or more other substances is called a chemicalproperty The ability of iron to form rust when combined with air is anexample of a chemical property of iron Similarly the inability of a substanceto change into another substance is also a chemical property For examplewhen iron is placed in nitrogen gas at room temperature no chemical changeoccurs The fact that iron does not undergo a change in the presence of nitro-gen is another chemical property of iron

Observing Properties of MatterEvery substance has its own unique set of physical and chemical propertiesTable 3-2 lists several of these properties of copper Figure 3-3 shows phys-ical and chemical properties of copper What physical and chemical proper-ties are evident in these photos

31 Properties of Matter 57

Figure 3-3

These photos illustrate some ofthe physical and chemical prop-erties of copper as it exists inthe form of hardware andthe Statue of Liberty b

a

Figure 3-2

Gold and pyrite or foolrsquosgold have similar physicalproperties but are different samples of matter

ba

Properties of Copper

Physical properties Chemical properties

Table 3-2a

b

a bGold Pyrite

bull Reddish brown shiny

bull Easily shaped into sheets (malleable) and drawn into wires(ductile)

bull Good conductor of heat and electricity

bull Density 892 gcm3

bull Melting point 1085degC

bull Boiling point 2570degC

bull Forms green copper carbonate compound when in contact withmoist air

bull Forms new substances when com-bined with nitric acid and sulfuricacid

bull Forms a deep blue solution whenin contact with ammonia

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Observations of properties may vary depending on the conditions of theimmediate environment It is important to state the specific conditions inwhich observations are made because both chemical and physical propertiesdepend on temperature and pressure Consider the properties of water forexample You may think of water as a liquid (physical property) that is notparticularly chemically reactive (chemical property) You may also know thatwater has a density of 100 gcm3 (physical property) These properties how-ever apply only to water at standard ldquoroomrdquo temperature and pressure At tem-peratures greater than 100degC water is a gas (physical property) with a densityof about 00006 gcm3 (physical property) that reacts rapidly with many dif-ferent substances (chemical property) As you can see the properties of waterare dramatically different under different conditions

States of MatterImagine you are sitting on a bench breathing heavily and drinking water aftera tiring game of soccer In this scenario you are in contact with three differentforms of matter the bench is a solid the water is a liquid and the air you breatheis a gas In fact all matter that exists on Earth can be classified as one of thesephysical forms called states of matter Scientists recognize a fourth state ofmatter called plasma but it does not occur naturally on Earth except in the formof lightning bolts The physical state of a substance is a physical property ofthat substance Each of the three common states of matter can be distinguishedby the way it fills a container

Solids A solid is a form of matter that has its own definite shape and vol-ume Wood iron paper and sugar are examples of solids The particles ofmatter in a solid are very tightly packed when heated a solid expands butonly slightly Because its shape is definite a solid may not conform to theshape of the container in which it is placed The tight packing of particles ina solid makes it incompressible that is it cannot be pressed into a smallervolume It is important to understand that a solid is not defined by its rigid-ity or hardness the marble statue in Figure 3-4 is rigid whereas wax sculp-ture is soft yet both are solids

Liquids A liquid is a form of matter that flows has constant volume andtakes the shape of its container Common examples of liquids include waterblood and mercury The particles in a liquid are not rigidly held in placeand are less closely packed than are the particles in a solid liquid particles

58 Chapter 3 MattermdashProperties and Changes

Figure 3-4

The properties of the solidmaterials marble and waxmake these sculptures possibleParticles in a solid are tightlypacked giving definite shapeand volume to the solid

c

ba

Solid

a b

c

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31 Properties of Matter 59

Figure 3-5

Despite having differentshapes each of these measuringcups holds the same volume ofliquid

River water flows to fitwithin the boundaries of itsbanks regardless of the curvesalong its path

Molecules in a liquid areclosely packed but can still moverelatively freely

c

b

a

Liquid

a bc

Figure 3-6

Molecules in a gas are farapart and freely moving

Neon gas completely fills the tubes of the electricartwork

b

a

are able to move past each other This allows a liquid to flow and take theshape of its container although it may not completely fill the container Aliquidrsquos volume is constant regardless of the size and shape of the containerin which the liquid is held the volume of the liquid remains the same Thisis why measuring cups used in cooking such as those pictured in Figure3-5 can be made in a variety of shapes yet still measure the same volumeBecause of the way the particles of a liquid are packed liquids are virtu-ally incompressible Like solids liquids tend to expand when heated

Gases A gas is a form of matter that flows to conform to the shape of itscontainer and fills the entire volume of its container Examples of gasesinclude neon which is used in the lighted artwork in Figure 3-6 methanewhich is used in cooking and air which is a mixture of gases Compared tosolids and liquids the particles of gases are very far apart Because of the sig-nificant amount of space between particles gases are easily compressed Theproblem-solving LAB in this section poses several important questions aboutthe practical use of compressed gas

It is likely that you are familiar with the word vapor as it relates to theword gas The words gas and vapor while similar do not mean the samething and should not be used interchangeably The word gas refers to a sub-stance that is naturally in thegaseous state at room temperatureThe word vapor refers to thegaseous state of a substance that isa solid or a liquid at room tempera-ture For example steam is a vaporbecause at room temperature waterexists as a liquid

bGasa

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60 Chapter 3 MattermdashProperties and Changes

Section 31 Assessment

1 Describe the characteristics that identify a sampleof matter as being a substance

2 Classify each of the following as a physical orchemical property

a Iron and oxygen form rustb Iron is more dense than aluminumc Magnesium burns brightly when ignitedd Oil and water do not mixe Mercury melts at 39degC

3 Create a table that describes the three commonstates of matter in terms of their shape volumeand compressibility

4 Thinking Critically Using what you know aboutthe compressibility of gases explain why the oxy-gen in a SCUBA tank is compressed

5 Interpreting Data Bromine is a reddish-brownliquid that boils at 59degC Bromine is highly reactivewith many metals For example it reacts withsodium to form a white solid Classify each of theseproperties of bromine as either a physical or achemical property

problem-solving LAB

How is compressed gasreleasedRecognizing Cause and Effect Tanks of com-pressed gases are a common sight in a chemistrylaboratory For example nitrogen is often flowedover a reaction in progress to displace othergases that might interfere with the experimentGiven what you know about the properties ofgases explain how compressed nitrogen isreleased

AnalysisBy definition the particles of gases are far apartand gases tend to fill their container even if thecontainer is a laboratory room Tanks of com-pressed gas come from the supplier capped toprevent the gas from escaping In the lab achemist or technician attaches a regulator to thetank and secures the tank to a stable fixture

Thinking Critically1 Explain why the flow of compressed gas must

be controlled for practical use

2 Predict what would happen if the valve on afull tank of compressed gas were suddenlyopened all the way or if the full tank werepunctured

The fact that substances can change form as in the example of waterchanging to steam is another important concept in chemistry If you reviewwhat you just learned about physical properties of substances you can seethat because the particular form of a substance is a physical property chang-ing the form introduces or adds another physical property to its list of char-acteristics In fact resources that provide tables of physical and chemicalproperties of substances such as the CRC Handbook of Chemistry and Physicsgenerally include the physical properties of substances in all of the states inwhich they can exist

chemistrymccomself_check_quiz

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32 Changes in Matter 61

Objectivesbull Define physical change and

list several common physicalchanges

bull Define chemical change andlist several indications that achemical change has takenplace

bull Apply the law of conserva-tion of mass to chemicalreactions

Vocabularyphysical changechemical changelaw of conservation of mass

Section Changes in Matter

You learned in Section 31 that scientists can describe matter in terms of phys-ical and chemical properties For example a physical property of copperallows it to be drawn into copper wire and a chemical property of copperaccounts for the fact that when a solution of copper ions is combined withammonia the copper solution changes to a deep blue color The key conceptin both of these examples is that the substance copper changed in some wayIn this section yoursquoll explore how matter changes as a result of its physicaland chemical properties

Physical ChangesA substance often undergoes changes that result in a dramatically differentappearance yet leave the composition of the substance unchanged An exam-ple is the crumpling of a sheet of aluminum foil While the foil goes from asmooth flat mirrorlike sheet to a round compact ball the actual composi-tion of the foil is unchangedmdashit is still aluminum Changes such as this whichalter a substance without changing its composition are known as physicalchanges Cutting a sheet of paper and breaking a crystal are other examplesof physical changes in matter Can you name some other physical changesYour list might include verbs such as bend grind crumple split and crushall of which indicate physical change

As with other physical properties the state of matter depends on the tem-perature and pressure of the surroundings As temperature and pressurechange most substances undergo a change from one state (or phase) toanother For example at atmospheric pressure and at temperatures below0degC water is in its solid state which is known as ice As heat is added to theice it melts and becomes liquid water This change of state is a physicalchange because even though ice and water have very different appearancestheir composition is the same If the temperature of the water increases to100degC the water begins to boil and liquid water is converted to steam Meltingand formation of a gas are both physical changes and phase changes Figure3-7 shows condensation another common phase change When you encounterterms such as boil freeze condense vaporize or melt in your study of chem-istry the meaning generally refers to a phase change in matter

32

a

Figure 3-7

Condensation on an icy bev-erage glass is the result of thephase change of water ina gaseous state to water in aliquid state

The characteristic ldquofogrdquo ofdry ice is actually fine waterdroplets formed by condensa-tion of water vapor from the airsurrounding the very cold dryice Refer to Table C-1 inAppendix C for a key to atomcolor conventions

b

a

b

a b

LAB

See page 953 in Appendix E forComparing Frozen Liquids

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The temperature and pressure at which a substance undergoes a phasechange are important physical properties These properties are listed as themelting and boiling points of the substance Table 3-1 on page 56 providesthis information for several common substances Like density the meltingpoint and boiling point are intensive physical properties that may be used toidentify unknown substances For example if an unknown solid melts at801degC and boils at 1413degCmdashvery high temperaturesmdashit is most probablysodium chloride or common table salt Tables of intensive properties suchas those given in the CRC Handbook of Chemistry and Physics are indis-pensable tools in identifying unknown substances from experimental data

Chemical ChangesAs you learned earlier chemical properties relate to the ability of a substanceto combine with or change into one or more substances A process thatinvolves one or more substances changing into new substances is called achemical change which is commonly referred to as a chemical reaction Thenew substances formed in the reaction have different compositions and dif-ferent properties from the substances present before the reaction occurred Forexample the crushing of grapes that is part of the wine-making process is aphysical change but the fermentation of the juice sugars and other ingredi-ents to wine is a chemical change The Chemistry and Society feature at theend of the chapter describes some interesting consequences of physical andchemical changes in the production of concrete

Letrsquos consider again the rusting of iron When a freshly exposed iron surface is left in contact with air it slowly changes into a new substancenamely the rust shown in Figure 3-8a The iron reacts with oxygen in the airto form a new substance rust Rust is a chemical combination of iron and oxy-gen In chemical reactions the starting substances are called reactants and thenew substances that are formed are called products Thus iron and oxygen arereactants and rust is a product When you encounter terms such as exploderust oxidize corrode tarnish ferment burn or rot the meaning generallyrefers to a chemical reaction in which reactant substances produce differentproduct substances

62 Chapter 3 MattermdashProperties and Changes

a

Figure 3-8

The formation of a gas orsolid when reactants mix oftenindicates that a chemical reac-tion has taken place Rust is theresult of a chemical reaction

Color changes generallyindicate that a chemical reactionhas taken place One example isthe color change of tree leavesin the fall

b

a

b

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Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

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64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

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32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

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Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

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17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

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16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

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10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 2: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

31 Properties of Matter 55

DISCOVERY LAB

Materials

large test tubetest-tube holder or rack10 mL HClzinc metalwood splintmatch or burner

Observing Chemical Change

Consider the metal objects that are part of the everyday world Amailbox for example stands outside day in and day out without

seeming to change Under what conditions does metal exhibit chem-ical change

Safety Precautions

Procedure

1 Place a piece of zinc metal in a large test tube

2 Add approximately 10 mL of 3M hydrochloric acid (HCl) to the testtube Record your observationsCAUTION HCI causes burns and hazardous fumes

3 When the zinc and HCl have reacted for approximately 1 minbring a lighted glowing wood splint to the mouth of the testtube CAUTION Be sure the test tube is facing away from yourface when the splint is brought near Again record yourobservations

Analysis

What may have caused the dynamic reaction you observed in step 3Did you expect this reaction Explain

Always wear eye goggles gloves and anapron when experimenting with chemicalsUse caution when handling an open flame

Objectivesbull Identify the characteristics

of a substance

bull Distinguish between physi-cal and chemical properties

bull Differentiate among thephysical states of matter

Vocabularysubstancephysical propertyextensive propertyintensive propertychemical propertystates of mattersolidliquidgasvapor

Section 31 Properties of Matter

Imagine yourself scuba diving through a complex biological ecosystem suchas a coral reef What kinds of things fill your imagination Regardless of whatyou envision there is only one answermdashyou see matter The diversity of mat-ter in the world and in the universe is astounding From pepperoni pizzas tosupernovas itrsquos all matter If we are to understand this diversity we must startwith a way of organizing and describing matter

SubstancesRecall from Chapter 1 that chemistry is the study of matter and matter isanything that has mass and takes up space Everything around you is mat-ter including things such as air and microbes which you cannot see Forexample table salt is a simple type of matter that you are probably familiarwith Table salt has a unique and unchanging chemical composition It isalways 100 sodium chloride and its composition does not change from onesample to another Matter that has a uniform and unchanging compositionis called a substance also known as a pure substance Table salt is a sub-stance Another example of a pure substance is water Water is always com-posed of hydrogen and oxygen Seawater on the other hand is not asubstance because samples taken from different locations will probably have

Chem MC-055

null

9278609

differing compositions That is they will contain differing amounts of watersalts and other dissolved substances Given this definition what other puresubstances are you familiar with Substances are important much of yourchemistry course will be focused on the processes by which substances arechanged into different substances

Physical Properties of MatterYou are used to identifying objects by their propertiesmdashtheir characteristicsand behavior For example you can easily identify a pencil in your backpackbecause you recognize its shape color weight or some other property Thesecharacteristics are all physical properties of the pencil A physical propertyis a characteristic that can be observed or measured without changing the sam-plersquos composition Physical properties describe pure substances too Becausesubstances have uniform and unchanging compositions they have consistentand unchanging physical properties as well Density color odor taste hard-ness melting point and boiling point are common physical properties thatscientists record as identifying characteristics of a substance Sodium chlo-ride forms solid white crystals at room temperature all having the sameunique salty taste Table 3-1 lists several common substances and their phys-ical properties

Extensive and intensive properties Physical properties can be furtherdescribed as being one of two types Extensive properties are dependent uponthe amount of substance present For example mass which depends on theamount of substance there is is an extensive property Length and volume arealso extensive properties Density on the other hand is an example of an inten-

sive property of matter Intensive properties are independentof the amount of substance present For example density of asubstance (at constant temperature and pressure) is the sameno matter how much substance is present

A substance can often be identified by its intensive prop-erties In some cases a single intensive property is uniqueenough for identification During the California gold rushminers relied on goldrsquos characteristic density (19 gcm3) toseparate valuable gold-containing flakes from riverbed sandThe process used by the miners is shown in Figure 3-1Another intensive property of gold is its distinctiveappearance Unfortunately miners often learned that iden-tification of gold based on appearance alone was mislead-ing Figure 3-2 shows a nugget of the relatively worthless

56 Chapter 3 MattermdashProperties and Changes

Figure 3-1

Miners relied on the physicalproperty of density to distin-guish gold (19 gcm3) from theworthless minerals in their sluicepans The density of pyrite aworthless mineral often mis-taken for gold is 5 gcm3

Physical Properties of Common Substances

State Melting Boiling DensitySubstance Color at 25degC point (degC) point (degC) (gcm3)

Oxygen Colorless Gas 218 ndash183 00014

Mercury Silver Liquid ndash39 357 135

Water Colorless Liquid 0 100 100

Sucrose White Solid 185 Decomposes 159

Sodium White Solid 801 1413 217chloride

Table 3-1

Science WriterDo you get excited about newsin science and technology Doyou like to explain informationin a way that others find inter-esting and understandableThen consider a career as a science writer

Science writers keep up-to-dateon what is happening in theworld of science and translatethat news so nonscientists canunderstand it These writerswork for newspapers maga-zines scientific publicationstelevision stations and Internetnews services Lots of curiosityas well as a degree in a scienceandor journalism is essential

Chem MC-056

null

17768661

mineral pyrite often called ldquofoolrsquos goldrdquo which looks very similar to actualgold nuggets Such errors in identification based on the intensive property ofappearance fooled many miners into falsely thinking they had struck it rich

Chemical Properties of MatterSome properties of a substance are not obvious unless the substance haschanged composition as a result of its contact with other substances or theapplication of thermal or electrical energy The ability of a substance to com-bine with or change into one or more other substances is called a chemicalproperty The ability of iron to form rust when combined with air is anexample of a chemical property of iron Similarly the inability of a substanceto change into another substance is also a chemical property For examplewhen iron is placed in nitrogen gas at room temperature no chemical changeoccurs The fact that iron does not undergo a change in the presence of nitro-gen is another chemical property of iron

Observing Properties of MatterEvery substance has its own unique set of physical and chemical propertiesTable 3-2 lists several of these properties of copper Figure 3-3 shows phys-ical and chemical properties of copper What physical and chemical proper-ties are evident in these photos

31 Properties of Matter 57

Figure 3-3

These photos illustrate some ofthe physical and chemical prop-erties of copper as it exists inthe form of hardware andthe Statue of Liberty b

a

Figure 3-2

Gold and pyrite or foolrsquosgold have similar physicalproperties but are different samples of matter

ba

Properties of Copper

Physical properties Chemical properties

Table 3-2a

b

a bGold Pyrite

bull Reddish brown shiny

bull Easily shaped into sheets (malleable) and drawn into wires(ductile)

bull Good conductor of heat and electricity

bull Density 892 gcm3

bull Melting point 1085degC

bull Boiling point 2570degC

bull Forms green copper carbonate compound when in contact withmoist air

bull Forms new substances when com-bined with nitric acid and sulfuricacid

bull Forms a deep blue solution whenin contact with ammonia

Chem MC-057

null

85837875

Observations of properties may vary depending on the conditions of theimmediate environment It is important to state the specific conditions inwhich observations are made because both chemical and physical propertiesdepend on temperature and pressure Consider the properties of water forexample You may think of water as a liquid (physical property) that is notparticularly chemically reactive (chemical property) You may also know thatwater has a density of 100 gcm3 (physical property) These properties how-ever apply only to water at standard ldquoroomrdquo temperature and pressure At tem-peratures greater than 100degC water is a gas (physical property) with a densityof about 00006 gcm3 (physical property) that reacts rapidly with many dif-ferent substances (chemical property) As you can see the properties of waterare dramatically different under different conditions

States of MatterImagine you are sitting on a bench breathing heavily and drinking water aftera tiring game of soccer In this scenario you are in contact with three differentforms of matter the bench is a solid the water is a liquid and the air you breatheis a gas In fact all matter that exists on Earth can be classified as one of thesephysical forms called states of matter Scientists recognize a fourth state ofmatter called plasma but it does not occur naturally on Earth except in the formof lightning bolts The physical state of a substance is a physical property ofthat substance Each of the three common states of matter can be distinguishedby the way it fills a container

Solids A solid is a form of matter that has its own definite shape and vol-ume Wood iron paper and sugar are examples of solids The particles ofmatter in a solid are very tightly packed when heated a solid expands butonly slightly Because its shape is definite a solid may not conform to theshape of the container in which it is placed The tight packing of particles ina solid makes it incompressible that is it cannot be pressed into a smallervolume It is important to understand that a solid is not defined by its rigid-ity or hardness the marble statue in Figure 3-4 is rigid whereas wax sculp-ture is soft yet both are solids

Liquids A liquid is a form of matter that flows has constant volume andtakes the shape of its container Common examples of liquids include waterblood and mercury The particles in a liquid are not rigidly held in placeand are less closely packed than are the particles in a solid liquid particles

58 Chapter 3 MattermdashProperties and Changes

Figure 3-4

The properties of the solidmaterials marble and waxmake these sculptures possibleParticles in a solid are tightlypacked giving definite shapeand volume to the solid

c

ba

Solid

a b

c

Chem MC-058

null

17444711

31 Properties of Matter 59

Figure 3-5

Despite having differentshapes each of these measuringcups holds the same volume ofliquid

River water flows to fitwithin the boundaries of itsbanks regardless of the curvesalong its path

Molecules in a liquid areclosely packed but can still moverelatively freely

c

b

a

Liquid

a bc

Figure 3-6

Molecules in a gas are farapart and freely moving

Neon gas completely fills the tubes of the electricartwork

b

a

are able to move past each other This allows a liquid to flow and take theshape of its container although it may not completely fill the container Aliquidrsquos volume is constant regardless of the size and shape of the containerin which the liquid is held the volume of the liquid remains the same Thisis why measuring cups used in cooking such as those pictured in Figure3-5 can be made in a variety of shapes yet still measure the same volumeBecause of the way the particles of a liquid are packed liquids are virtu-ally incompressible Like solids liquids tend to expand when heated

Gases A gas is a form of matter that flows to conform to the shape of itscontainer and fills the entire volume of its container Examples of gasesinclude neon which is used in the lighted artwork in Figure 3-6 methanewhich is used in cooking and air which is a mixture of gases Compared tosolids and liquids the particles of gases are very far apart Because of the sig-nificant amount of space between particles gases are easily compressed Theproblem-solving LAB in this section poses several important questions aboutthe practical use of compressed gas

It is likely that you are familiar with the word vapor as it relates to theword gas The words gas and vapor while similar do not mean the samething and should not be used interchangeably The word gas refers to a sub-stance that is naturally in thegaseous state at room temperatureThe word vapor refers to thegaseous state of a substance that isa solid or a liquid at room tempera-ture For example steam is a vaporbecause at room temperature waterexists as a liquid

bGasa

Chem MC-059

null

11253363

60 Chapter 3 MattermdashProperties and Changes

Section 31 Assessment

1 Describe the characteristics that identify a sampleof matter as being a substance

2 Classify each of the following as a physical orchemical property

a Iron and oxygen form rustb Iron is more dense than aluminumc Magnesium burns brightly when ignitedd Oil and water do not mixe Mercury melts at 39degC

3 Create a table that describes the three commonstates of matter in terms of their shape volumeand compressibility

4 Thinking Critically Using what you know aboutthe compressibility of gases explain why the oxy-gen in a SCUBA tank is compressed

5 Interpreting Data Bromine is a reddish-brownliquid that boils at 59degC Bromine is highly reactivewith many metals For example it reacts withsodium to form a white solid Classify each of theseproperties of bromine as either a physical or achemical property

problem-solving LAB

How is compressed gasreleasedRecognizing Cause and Effect Tanks of com-pressed gases are a common sight in a chemistrylaboratory For example nitrogen is often flowedover a reaction in progress to displace othergases that might interfere with the experimentGiven what you know about the properties ofgases explain how compressed nitrogen isreleased

AnalysisBy definition the particles of gases are far apartand gases tend to fill their container even if thecontainer is a laboratory room Tanks of com-pressed gas come from the supplier capped toprevent the gas from escaping In the lab achemist or technician attaches a regulator to thetank and secures the tank to a stable fixture

Thinking Critically1 Explain why the flow of compressed gas must

be controlled for practical use

2 Predict what would happen if the valve on afull tank of compressed gas were suddenlyopened all the way or if the full tank werepunctured

The fact that substances can change form as in the example of waterchanging to steam is another important concept in chemistry If you reviewwhat you just learned about physical properties of substances you can seethat because the particular form of a substance is a physical property chang-ing the form introduces or adds another physical property to its list of char-acteristics In fact resources that provide tables of physical and chemicalproperties of substances such as the CRC Handbook of Chemistry and Physicsgenerally include the physical properties of substances in all of the states inwhich they can exist

chemistrymccomself_check_quiz

Chem MC-060

null

38870155

32 Changes in Matter 61

Objectivesbull Define physical change and

list several common physicalchanges

bull Define chemical change andlist several indications that achemical change has takenplace

bull Apply the law of conserva-tion of mass to chemicalreactions

Vocabularyphysical changechemical changelaw of conservation of mass

Section Changes in Matter

You learned in Section 31 that scientists can describe matter in terms of phys-ical and chemical properties For example a physical property of copperallows it to be drawn into copper wire and a chemical property of copperaccounts for the fact that when a solution of copper ions is combined withammonia the copper solution changes to a deep blue color The key conceptin both of these examples is that the substance copper changed in some wayIn this section yoursquoll explore how matter changes as a result of its physicaland chemical properties

Physical ChangesA substance often undergoes changes that result in a dramatically differentappearance yet leave the composition of the substance unchanged An exam-ple is the crumpling of a sheet of aluminum foil While the foil goes from asmooth flat mirrorlike sheet to a round compact ball the actual composi-tion of the foil is unchangedmdashit is still aluminum Changes such as this whichalter a substance without changing its composition are known as physicalchanges Cutting a sheet of paper and breaking a crystal are other examplesof physical changes in matter Can you name some other physical changesYour list might include verbs such as bend grind crumple split and crushall of which indicate physical change

As with other physical properties the state of matter depends on the tem-perature and pressure of the surroundings As temperature and pressurechange most substances undergo a change from one state (or phase) toanother For example at atmospheric pressure and at temperatures below0degC water is in its solid state which is known as ice As heat is added to theice it melts and becomes liquid water This change of state is a physicalchange because even though ice and water have very different appearancestheir composition is the same If the temperature of the water increases to100degC the water begins to boil and liquid water is converted to steam Meltingand formation of a gas are both physical changes and phase changes Figure3-7 shows condensation another common phase change When you encounterterms such as boil freeze condense vaporize or melt in your study of chem-istry the meaning generally refers to a phase change in matter

32

a

Figure 3-7

Condensation on an icy bev-erage glass is the result of thephase change of water ina gaseous state to water in aliquid state

The characteristic ldquofogrdquo ofdry ice is actually fine waterdroplets formed by condensa-tion of water vapor from the airsurrounding the very cold dryice Refer to Table C-1 inAppendix C for a key to atomcolor conventions

b

a

b

a b

LAB

See page 953 in Appendix E forComparing Frozen Liquids

Chem MC-061

null

15443536

CMC_Spn_C03-S02

null

4174369

The temperature and pressure at which a substance undergoes a phasechange are important physical properties These properties are listed as themelting and boiling points of the substance Table 3-1 on page 56 providesthis information for several common substances Like density the meltingpoint and boiling point are intensive physical properties that may be used toidentify unknown substances For example if an unknown solid melts at801degC and boils at 1413degCmdashvery high temperaturesmdashit is most probablysodium chloride or common table salt Tables of intensive properties suchas those given in the CRC Handbook of Chemistry and Physics are indis-pensable tools in identifying unknown substances from experimental data

Chemical ChangesAs you learned earlier chemical properties relate to the ability of a substanceto combine with or change into one or more substances A process thatinvolves one or more substances changing into new substances is called achemical change which is commonly referred to as a chemical reaction Thenew substances formed in the reaction have different compositions and dif-ferent properties from the substances present before the reaction occurred Forexample the crushing of grapes that is part of the wine-making process is aphysical change but the fermentation of the juice sugars and other ingredi-ents to wine is a chemical change The Chemistry and Society feature at theend of the chapter describes some interesting consequences of physical andchemical changes in the production of concrete

Letrsquos consider again the rusting of iron When a freshly exposed iron surface is left in contact with air it slowly changes into a new substancenamely the rust shown in Figure 3-8a The iron reacts with oxygen in the airto form a new substance rust Rust is a chemical combination of iron and oxy-gen In chemical reactions the starting substances are called reactants and thenew substances that are formed are called products Thus iron and oxygen arereactants and rust is a product When you encounter terms such as exploderust oxidize corrode tarnish ferment burn or rot the meaning generallyrefers to a chemical reaction in which reactant substances produce differentproduct substances

62 Chapter 3 MattermdashProperties and Changes

a

Figure 3-8

The formation of a gas orsolid when reactants mix oftenindicates that a chemical reac-tion has taken place Rust is theresult of a chemical reaction

Color changes generallyindicate that a chemical reactionhas taken place One example isthe color change of tree leavesin the fall

b

a

b

Chem MC-062

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14978511

Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

Chem MC-063

null

1447691

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

null

4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

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14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

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10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

null

16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 3: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

differing compositions That is they will contain differing amounts of watersalts and other dissolved substances Given this definition what other puresubstances are you familiar with Substances are important much of yourchemistry course will be focused on the processes by which substances arechanged into different substances

Physical Properties of MatterYou are used to identifying objects by their propertiesmdashtheir characteristicsand behavior For example you can easily identify a pencil in your backpackbecause you recognize its shape color weight or some other property Thesecharacteristics are all physical properties of the pencil A physical propertyis a characteristic that can be observed or measured without changing the sam-plersquos composition Physical properties describe pure substances too Becausesubstances have uniform and unchanging compositions they have consistentand unchanging physical properties as well Density color odor taste hard-ness melting point and boiling point are common physical properties thatscientists record as identifying characteristics of a substance Sodium chlo-ride forms solid white crystals at room temperature all having the sameunique salty taste Table 3-1 lists several common substances and their phys-ical properties

Extensive and intensive properties Physical properties can be furtherdescribed as being one of two types Extensive properties are dependent uponthe amount of substance present For example mass which depends on theamount of substance there is is an extensive property Length and volume arealso extensive properties Density on the other hand is an example of an inten-

sive property of matter Intensive properties are independentof the amount of substance present For example density of asubstance (at constant temperature and pressure) is the sameno matter how much substance is present

A substance can often be identified by its intensive prop-erties In some cases a single intensive property is uniqueenough for identification During the California gold rushminers relied on goldrsquos characteristic density (19 gcm3) toseparate valuable gold-containing flakes from riverbed sandThe process used by the miners is shown in Figure 3-1Another intensive property of gold is its distinctiveappearance Unfortunately miners often learned that iden-tification of gold based on appearance alone was mislead-ing Figure 3-2 shows a nugget of the relatively worthless

56 Chapter 3 MattermdashProperties and Changes

Figure 3-1

Miners relied on the physicalproperty of density to distin-guish gold (19 gcm3) from theworthless minerals in their sluicepans The density of pyrite aworthless mineral often mis-taken for gold is 5 gcm3

Physical Properties of Common Substances

State Melting Boiling DensitySubstance Color at 25degC point (degC) point (degC) (gcm3)

Oxygen Colorless Gas 218 ndash183 00014

Mercury Silver Liquid ndash39 357 135

Water Colorless Liquid 0 100 100

Sucrose White Solid 185 Decomposes 159

Sodium White Solid 801 1413 217chloride

Table 3-1

Science WriterDo you get excited about newsin science and technology Doyou like to explain informationin a way that others find inter-esting and understandableThen consider a career as a science writer

Science writers keep up-to-dateon what is happening in theworld of science and translatethat news so nonscientists canunderstand it These writerswork for newspapers maga-zines scientific publicationstelevision stations and Internetnews services Lots of curiosityas well as a degree in a scienceandor journalism is essential

Chem MC-056

null

17768661

mineral pyrite often called ldquofoolrsquos goldrdquo which looks very similar to actualgold nuggets Such errors in identification based on the intensive property ofappearance fooled many miners into falsely thinking they had struck it rich

Chemical Properties of MatterSome properties of a substance are not obvious unless the substance haschanged composition as a result of its contact with other substances or theapplication of thermal or electrical energy The ability of a substance to com-bine with or change into one or more other substances is called a chemicalproperty The ability of iron to form rust when combined with air is anexample of a chemical property of iron Similarly the inability of a substanceto change into another substance is also a chemical property For examplewhen iron is placed in nitrogen gas at room temperature no chemical changeoccurs The fact that iron does not undergo a change in the presence of nitro-gen is another chemical property of iron

Observing Properties of MatterEvery substance has its own unique set of physical and chemical propertiesTable 3-2 lists several of these properties of copper Figure 3-3 shows phys-ical and chemical properties of copper What physical and chemical proper-ties are evident in these photos

31 Properties of Matter 57

Figure 3-3

These photos illustrate some ofthe physical and chemical prop-erties of copper as it exists inthe form of hardware andthe Statue of Liberty b

a

Figure 3-2

Gold and pyrite or foolrsquosgold have similar physicalproperties but are different samples of matter

ba

Properties of Copper

Physical properties Chemical properties

Table 3-2a

b

a bGold Pyrite

bull Reddish brown shiny

bull Easily shaped into sheets (malleable) and drawn into wires(ductile)

bull Good conductor of heat and electricity

bull Density 892 gcm3

bull Melting point 1085degC

bull Boiling point 2570degC

bull Forms green copper carbonate compound when in contact withmoist air

bull Forms new substances when com-bined with nitric acid and sulfuricacid

bull Forms a deep blue solution whenin contact with ammonia

Chem MC-057

null

85837875

Observations of properties may vary depending on the conditions of theimmediate environment It is important to state the specific conditions inwhich observations are made because both chemical and physical propertiesdepend on temperature and pressure Consider the properties of water forexample You may think of water as a liquid (physical property) that is notparticularly chemically reactive (chemical property) You may also know thatwater has a density of 100 gcm3 (physical property) These properties how-ever apply only to water at standard ldquoroomrdquo temperature and pressure At tem-peratures greater than 100degC water is a gas (physical property) with a densityof about 00006 gcm3 (physical property) that reacts rapidly with many dif-ferent substances (chemical property) As you can see the properties of waterare dramatically different under different conditions

States of MatterImagine you are sitting on a bench breathing heavily and drinking water aftera tiring game of soccer In this scenario you are in contact with three differentforms of matter the bench is a solid the water is a liquid and the air you breatheis a gas In fact all matter that exists on Earth can be classified as one of thesephysical forms called states of matter Scientists recognize a fourth state ofmatter called plasma but it does not occur naturally on Earth except in the formof lightning bolts The physical state of a substance is a physical property ofthat substance Each of the three common states of matter can be distinguishedby the way it fills a container

Solids A solid is a form of matter that has its own definite shape and vol-ume Wood iron paper and sugar are examples of solids The particles ofmatter in a solid are very tightly packed when heated a solid expands butonly slightly Because its shape is definite a solid may not conform to theshape of the container in which it is placed The tight packing of particles ina solid makes it incompressible that is it cannot be pressed into a smallervolume It is important to understand that a solid is not defined by its rigid-ity or hardness the marble statue in Figure 3-4 is rigid whereas wax sculp-ture is soft yet both are solids

Liquids A liquid is a form of matter that flows has constant volume andtakes the shape of its container Common examples of liquids include waterblood and mercury The particles in a liquid are not rigidly held in placeand are less closely packed than are the particles in a solid liquid particles

58 Chapter 3 MattermdashProperties and Changes

Figure 3-4

The properties of the solidmaterials marble and waxmake these sculptures possibleParticles in a solid are tightlypacked giving definite shapeand volume to the solid

c

ba

Solid

a b

c

Chem MC-058

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17444711

31 Properties of Matter 59

Figure 3-5

Despite having differentshapes each of these measuringcups holds the same volume ofliquid

River water flows to fitwithin the boundaries of itsbanks regardless of the curvesalong its path

Molecules in a liquid areclosely packed but can still moverelatively freely

c

b

a

Liquid

a bc

Figure 3-6

Molecules in a gas are farapart and freely moving

Neon gas completely fills the tubes of the electricartwork

b

a

are able to move past each other This allows a liquid to flow and take theshape of its container although it may not completely fill the container Aliquidrsquos volume is constant regardless of the size and shape of the containerin which the liquid is held the volume of the liquid remains the same Thisis why measuring cups used in cooking such as those pictured in Figure3-5 can be made in a variety of shapes yet still measure the same volumeBecause of the way the particles of a liquid are packed liquids are virtu-ally incompressible Like solids liquids tend to expand when heated

Gases A gas is a form of matter that flows to conform to the shape of itscontainer and fills the entire volume of its container Examples of gasesinclude neon which is used in the lighted artwork in Figure 3-6 methanewhich is used in cooking and air which is a mixture of gases Compared tosolids and liquids the particles of gases are very far apart Because of the sig-nificant amount of space between particles gases are easily compressed Theproblem-solving LAB in this section poses several important questions aboutthe practical use of compressed gas

It is likely that you are familiar with the word vapor as it relates to theword gas The words gas and vapor while similar do not mean the samething and should not be used interchangeably The word gas refers to a sub-stance that is naturally in thegaseous state at room temperatureThe word vapor refers to thegaseous state of a substance that isa solid or a liquid at room tempera-ture For example steam is a vaporbecause at room temperature waterexists as a liquid

bGasa

Chem MC-059

null

11253363

60 Chapter 3 MattermdashProperties and Changes

Section 31 Assessment

1 Describe the characteristics that identify a sampleof matter as being a substance

2 Classify each of the following as a physical orchemical property

a Iron and oxygen form rustb Iron is more dense than aluminumc Magnesium burns brightly when ignitedd Oil and water do not mixe Mercury melts at 39degC

3 Create a table that describes the three commonstates of matter in terms of their shape volumeand compressibility

4 Thinking Critically Using what you know aboutthe compressibility of gases explain why the oxy-gen in a SCUBA tank is compressed

5 Interpreting Data Bromine is a reddish-brownliquid that boils at 59degC Bromine is highly reactivewith many metals For example it reacts withsodium to form a white solid Classify each of theseproperties of bromine as either a physical or achemical property

problem-solving LAB

How is compressed gasreleasedRecognizing Cause and Effect Tanks of com-pressed gases are a common sight in a chemistrylaboratory For example nitrogen is often flowedover a reaction in progress to displace othergases that might interfere with the experimentGiven what you know about the properties ofgases explain how compressed nitrogen isreleased

AnalysisBy definition the particles of gases are far apartand gases tend to fill their container even if thecontainer is a laboratory room Tanks of com-pressed gas come from the supplier capped toprevent the gas from escaping In the lab achemist or technician attaches a regulator to thetank and secures the tank to a stable fixture

Thinking Critically1 Explain why the flow of compressed gas must

be controlled for practical use

2 Predict what would happen if the valve on afull tank of compressed gas were suddenlyopened all the way or if the full tank werepunctured

The fact that substances can change form as in the example of waterchanging to steam is another important concept in chemistry If you reviewwhat you just learned about physical properties of substances you can seethat because the particular form of a substance is a physical property chang-ing the form introduces or adds another physical property to its list of char-acteristics In fact resources that provide tables of physical and chemicalproperties of substances such as the CRC Handbook of Chemistry and Physicsgenerally include the physical properties of substances in all of the states inwhich they can exist

chemistrymccomself_check_quiz

Chem MC-060

null

38870155

32 Changes in Matter 61

Objectivesbull Define physical change and

list several common physicalchanges

bull Define chemical change andlist several indications that achemical change has takenplace

bull Apply the law of conserva-tion of mass to chemicalreactions

Vocabularyphysical changechemical changelaw of conservation of mass

Section Changes in Matter

You learned in Section 31 that scientists can describe matter in terms of phys-ical and chemical properties For example a physical property of copperallows it to be drawn into copper wire and a chemical property of copperaccounts for the fact that when a solution of copper ions is combined withammonia the copper solution changes to a deep blue color The key conceptin both of these examples is that the substance copper changed in some wayIn this section yoursquoll explore how matter changes as a result of its physicaland chemical properties

Physical ChangesA substance often undergoes changes that result in a dramatically differentappearance yet leave the composition of the substance unchanged An exam-ple is the crumpling of a sheet of aluminum foil While the foil goes from asmooth flat mirrorlike sheet to a round compact ball the actual composi-tion of the foil is unchangedmdashit is still aluminum Changes such as this whichalter a substance without changing its composition are known as physicalchanges Cutting a sheet of paper and breaking a crystal are other examplesof physical changes in matter Can you name some other physical changesYour list might include verbs such as bend grind crumple split and crushall of which indicate physical change

As with other physical properties the state of matter depends on the tem-perature and pressure of the surroundings As temperature and pressurechange most substances undergo a change from one state (or phase) toanother For example at atmospheric pressure and at temperatures below0degC water is in its solid state which is known as ice As heat is added to theice it melts and becomes liquid water This change of state is a physicalchange because even though ice and water have very different appearancestheir composition is the same If the temperature of the water increases to100degC the water begins to boil and liquid water is converted to steam Meltingand formation of a gas are both physical changes and phase changes Figure3-7 shows condensation another common phase change When you encounterterms such as boil freeze condense vaporize or melt in your study of chem-istry the meaning generally refers to a phase change in matter

32

a

Figure 3-7

Condensation on an icy bev-erage glass is the result of thephase change of water ina gaseous state to water in aliquid state

The characteristic ldquofogrdquo ofdry ice is actually fine waterdroplets formed by condensa-tion of water vapor from the airsurrounding the very cold dryice Refer to Table C-1 inAppendix C for a key to atomcolor conventions

b

a

b

a b

LAB

See page 953 in Appendix E forComparing Frozen Liquids

Chem MC-061

null

15443536

CMC_Spn_C03-S02

null

4174369

The temperature and pressure at which a substance undergoes a phasechange are important physical properties These properties are listed as themelting and boiling points of the substance Table 3-1 on page 56 providesthis information for several common substances Like density the meltingpoint and boiling point are intensive physical properties that may be used toidentify unknown substances For example if an unknown solid melts at801degC and boils at 1413degCmdashvery high temperaturesmdashit is most probablysodium chloride or common table salt Tables of intensive properties suchas those given in the CRC Handbook of Chemistry and Physics are indis-pensable tools in identifying unknown substances from experimental data

Chemical ChangesAs you learned earlier chemical properties relate to the ability of a substanceto combine with or change into one or more substances A process thatinvolves one or more substances changing into new substances is called achemical change which is commonly referred to as a chemical reaction Thenew substances formed in the reaction have different compositions and dif-ferent properties from the substances present before the reaction occurred Forexample the crushing of grapes that is part of the wine-making process is aphysical change but the fermentation of the juice sugars and other ingredi-ents to wine is a chemical change The Chemistry and Society feature at theend of the chapter describes some interesting consequences of physical andchemical changes in the production of concrete

Letrsquos consider again the rusting of iron When a freshly exposed iron surface is left in contact with air it slowly changes into a new substancenamely the rust shown in Figure 3-8a The iron reacts with oxygen in the airto form a new substance rust Rust is a chemical combination of iron and oxy-gen In chemical reactions the starting substances are called reactants and thenew substances that are formed are called products Thus iron and oxygen arereactants and rust is a product When you encounter terms such as exploderust oxidize corrode tarnish ferment burn or rot the meaning generallyrefers to a chemical reaction in which reactant substances produce differentproduct substances

62 Chapter 3 MattermdashProperties and Changes

a

Figure 3-8

The formation of a gas orsolid when reactants mix oftenindicates that a chemical reac-tion has taken place Rust is theresult of a chemical reaction

Color changes generallyindicate that a chemical reactionhas taken place One example isthe color change of tree leavesin the fall

b

a

b

Chem MC-062

null

14978511

Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

Chem MC-063

null

1447691

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

null

4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

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14105936

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Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

null

16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
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                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
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Page 4: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

mineral pyrite often called ldquofoolrsquos goldrdquo which looks very similar to actualgold nuggets Such errors in identification based on the intensive property ofappearance fooled many miners into falsely thinking they had struck it rich

Chemical Properties of MatterSome properties of a substance are not obvious unless the substance haschanged composition as a result of its contact with other substances or theapplication of thermal or electrical energy The ability of a substance to com-bine with or change into one or more other substances is called a chemicalproperty The ability of iron to form rust when combined with air is anexample of a chemical property of iron Similarly the inability of a substanceto change into another substance is also a chemical property For examplewhen iron is placed in nitrogen gas at room temperature no chemical changeoccurs The fact that iron does not undergo a change in the presence of nitro-gen is another chemical property of iron

Observing Properties of MatterEvery substance has its own unique set of physical and chemical propertiesTable 3-2 lists several of these properties of copper Figure 3-3 shows phys-ical and chemical properties of copper What physical and chemical proper-ties are evident in these photos

31 Properties of Matter 57

Figure 3-3

These photos illustrate some ofthe physical and chemical prop-erties of copper as it exists inthe form of hardware andthe Statue of Liberty b

a

Figure 3-2

Gold and pyrite or foolrsquosgold have similar physicalproperties but are different samples of matter

ba

Properties of Copper

Physical properties Chemical properties

Table 3-2a

b

a bGold Pyrite

bull Reddish brown shiny

bull Easily shaped into sheets (malleable) and drawn into wires(ductile)

bull Good conductor of heat and electricity

bull Density 892 gcm3

bull Melting point 1085degC

bull Boiling point 2570degC

bull Forms green copper carbonate compound when in contact withmoist air

bull Forms new substances when com-bined with nitric acid and sulfuricacid

bull Forms a deep blue solution whenin contact with ammonia

Chem MC-057

null

85837875

Observations of properties may vary depending on the conditions of theimmediate environment It is important to state the specific conditions inwhich observations are made because both chemical and physical propertiesdepend on temperature and pressure Consider the properties of water forexample You may think of water as a liquid (physical property) that is notparticularly chemically reactive (chemical property) You may also know thatwater has a density of 100 gcm3 (physical property) These properties how-ever apply only to water at standard ldquoroomrdquo temperature and pressure At tem-peratures greater than 100degC water is a gas (physical property) with a densityof about 00006 gcm3 (physical property) that reacts rapidly with many dif-ferent substances (chemical property) As you can see the properties of waterare dramatically different under different conditions

States of MatterImagine you are sitting on a bench breathing heavily and drinking water aftera tiring game of soccer In this scenario you are in contact with three differentforms of matter the bench is a solid the water is a liquid and the air you breatheis a gas In fact all matter that exists on Earth can be classified as one of thesephysical forms called states of matter Scientists recognize a fourth state ofmatter called plasma but it does not occur naturally on Earth except in the formof lightning bolts The physical state of a substance is a physical property ofthat substance Each of the three common states of matter can be distinguishedby the way it fills a container

Solids A solid is a form of matter that has its own definite shape and vol-ume Wood iron paper and sugar are examples of solids The particles ofmatter in a solid are very tightly packed when heated a solid expands butonly slightly Because its shape is definite a solid may not conform to theshape of the container in which it is placed The tight packing of particles ina solid makes it incompressible that is it cannot be pressed into a smallervolume It is important to understand that a solid is not defined by its rigid-ity or hardness the marble statue in Figure 3-4 is rigid whereas wax sculp-ture is soft yet both are solids

Liquids A liquid is a form of matter that flows has constant volume andtakes the shape of its container Common examples of liquids include waterblood and mercury The particles in a liquid are not rigidly held in placeand are less closely packed than are the particles in a solid liquid particles

58 Chapter 3 MattermdashProperties and Changes

Figure 3-4

The properties of the solidmaterials marble and waxmake these sculptures possibleParticles in a solid are tightlypacked giving definite shapeand volume to the solid

c

ba

Solid

a b

c

Chem MC-058

null

17444711

31 Properties of Matter 59

Figure 3-5

Despite having differentshapes each of these measuringcups holds the same volume ofliquid

River water flows to fitwithin the boundaries of itsbanks regardless of the curvesalong its path

Molecules in a liquid areclosely packed but can still moverelatively freely

c

b

a

Liquid

a bc

Figure 3-6

Molecules in a gas are farapart and freely moving

Neon gas completely fills the tubes of the electricartwork

b

a

are able to move past each other This allows a liquid to flow and take theshape of its container although it may not completely fill the container Aliquidrsquos volume is constant regardless of the size and shape of the containerin which the liquid is held the volume of the liquid remains the same Thisis why measuring cups used in cooking such as those pictured in Figure3-5 can be made in a variety of shapes yet still measure the same volumeBecause of the way the particles of a liquid are packed liquids are virtu-ally incompressible Like solids liquids tend to expand when heated

Gases A gas is a form of matter that flows to conform to the shape of itscontainer and fills the entire volume of its container Examples of gasesinclude neon which is used in the lighted artwork in Figure 3-6 methanewhich is used in cooking and air which is a mixture of gases Compared tosolids and liquids the particles of gases are very far apart Because of the sig-nificant amount of space between particles gases are easily compressed Theproblem-solving LAB in this section poses several important questions aboutthe practical use of compressed gas

It is likely that you are familiar with the word vapor as it relates to theword gas The words gas and vapor while similar do not mean the samething and should not be used interchangeably The word gas refers to a sub-stance that is naturally in thegaseous state at room temperatureThe word vapor refers to thegaseous state of a substance that isa solid or a liquid at room tempera-ture For example steam is a vaporbecause at room temperature waterexists as a liquid

bGasa

Chem MC-059

null

11253363

60 Chapter 3 MattermdashProperties and Changes

Section 31 Assessment

1 Describe the characteristics that identify a sampleof matter as being a substance

2 Classify each of the following as a physical orchemical property

a Iron and oxygen form rustb Iron is more dense than aluminumc Magnesium burns brightly when ignitedd Oil and water do not mixe Mercury melts at 39degC

3 Create a table that describes the three commonstates of matter in terms of their shape volumeand compressibility

4 Thinking Critically Using what you know aboutthe compressibility of gases explain why the oxy-gen in a SCUBA tank is compressed

5 Interpreting Data Bromine is a reddish-brownliquid that boils at 59degC Bromine is highly reactivewith many metals For example it reacts withsodium to form a white solid Classify each of theseproperties of bromine as either a physical or achemical property

problem-solving LAB

How is compressed gasreleasedRecognizing Cause and Effect Tanks of com-pressed gases are a common sight in a chemistrylaboratory For example nitrogen is often flowedover a reaction in progress to displace othergases that might interfere with the experimentGiven what you know about the properties ofgases explain how compressed nitrogen isreleased

AnalysisBy definition the particles of gases are far apartand gases tend to fill their container even if thecontainer is a laboratory room Tanks of com-pressed gas come from the supplier capped toprevent the gas from escaping In the lab achemist or technician attaches a regulator to thetank and secures the tank to a stable fixture

Thinking Critically1 Explain why the flow of compressed gas must

be controlled for practical use

2 Predict what would happen if the valve on afull tank of compressed gas were suddenlyopened all the way or if the full tank werepunctured

The fact that substances can change form as in the example of waterchanging to steam is another important concept in chemistry If you reviewwhat you just learned about physical properties of substances you can seethat because the particular form of a substance is a physical property chang-ing the form introduces or adds another physical property to its list of char-acteristics In fact resources that provide tables of physical and chemicalproperties of substances such as the CRC Handbook of Chemistry and Physicsgenerally include the physical properties of substances in all of the states inwhich they can exist

chemistrymccomself_check_quiz

Chem MC-060

null

38870155

32 Changes in Matter 61

Objectivesbull Define physical change and

list several common physicalchanges

bull Define chemical change andlist several indications that achemical change has takenplace

bull Apply the law of conserva-tion of mass to chemicalreactions

Vocabularyphysical changechemical changelaw of conservation of mass

Section Changes in Matter

You learned in Section 31 that scientists can describe matter in terms of phys-ical and chemical properties For example a physical property of copperallows it to be drawn into copper wire and a chemical property of copperaccounts for the fact that when a solution of copper ions is combined withammonia the copper solution changes to a deep blue color The key conceptin both of these examples is that the substance copper changed in some wayIn this section yoursquoll explore how matter changes as a result of its physicaland chemical properties

Physical ChangesA substance often undergoes changes that result in a dramatically differentappearance yet leave the composition of the substance unchanged An exam-ple is the crumpling of a sheet of aluminum foil While the foil goes from asmooth flat mirrorlike sheet to a round compact ball the actual composi-tion of the foil is unchangedmdashit is still aluminum Changes such as this whichalter a substance without changing its composition are known as physicalchanges Cutting a sheet of paper and breaking a crystal are other examplesof physical changes in matter Can you name some other physical changesYour list might include verbs such as bend grind crumple split and crushall of which indicate physical change

As with other physical properties the state of matter depends on the tem-perature and pressure of the surroundings As temperature and pressurechange most substances undergo a change from one state (or phase) toanother For example at atmospheric pressure and at temperatures below0degC water is in its solid state which is known as ice As heat is added to theice it melts and becomes liquid water This change of state is a physicalchange because even though ice and water have very different appearancestheir composition is the same If the temperature of the water increases to100degC the water begins to boil and liquid water is converted to steam Meltingand formation of a gas are both physical changes and phase changes Figure3-7 shows condensation another common phase change When you encounterterms such as boil freeze condense vaporize or melt in your study of chem-istry the meaning generally refers to a phase change in matter

32

a

Figure 3-7

Condensation on an icy bev-erage glass is the result of thephase change of water ina gaseous state to water in aliquid state

The characteristic ldquofogrdquo ofdry ice is actually fine waterdroplets formed by condensa-tion of water vapor from the airsurrounding the very cold dryice Refer to Table C-1 inAppendix C for a key to atomcolor conventions

b

a

b

a b

LAB

See page 953 in Appendix E forComparing Frozen Liquids

Chem MC-061

null

15443536

CMC_Spn_C03-S02

null

4174369

The temperature and pressure at which a substance undergoes a phasechange are important physical properties These properties are listed as themelting and boiling points of the substance Table 3-1 on page 56 providesthis information for several common substances Like density the meltingpoint and boiling point are intensive physical properties that may be used toidentify unknown substances For example if an unknown solid melts at801degC and boils at 1413degCmdashvery high temperaturesmdashit is most probablysodium chloride or common table salt Tables of intensive properties suchas those given in the CRC Handbook of Chemistry and Physics are indis-pensable tools in identifying unknown substances from experimental data

Chemical ChangesAs you learned earlier chemical properties relate to the ability of a substanceto combine with or change into one or more substances A process thatinvolves one or more substances changing into new substances is called achemical change which is commonly referred to as a chemical reaction Thenew substances formed in the reaction have different compositions and dif-ferent properties from the substances present before the reaction occurred Forexample the crushing of grapes that is part of the wine-making process is aphysical change but the fermentation of the juice sugars and other ingredi-ents to wine is a chemical change The Chemistry and Society feature at theend of the chapter describes some interesting consequences of physical andchemical changes in the production of concrete

Letrsquos consider again the rusting of iron When a freshly exposed iron surface is left in contact with air it slowly changes into a new substancenamely the rust shown in Figure 3-8a The iron reacts with oxygen in the airto form a new substance rust Rust is a chemical combination of iron and oxy-gen In chemical reactions the starting substances are called reactants and thenew substances that are formed are called products Thus iron and oxygen arereactants and rust is a product When you encounter terms such as exploderust oxidize corrode tarnish ferment burn or rot the meaning generallyrefers to a chemical reaction in which reactant substances produce differentproduct substances

62 Chapter 3 MattermdashProperties and Changes

a

Figure 3-8

The formation of a gas orsolid when reactants mix oftenindicates that a chemical reac-tion has taken place Rust is theresult of a chemical reaction

Color changes generallyindicate that a chemical reactionhas taken place One example isthe color change of tree leavesin the fall

b

a

b

Chem MC-062

null

14978511

Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

Chem MC-063

null

1447691

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

null

4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

null

14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

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16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 5: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Observations of properties may vary depending on the conditions of theimmediate environment It is important to state the specific conditions inwhich observations are made because both chemical and physical propertiesdepend on temperature and pressure Consider the properties of water forexample You may think of water as a liquid (physical property) that is notparticularly chemically reactive (chemical property) You may also know thatwater has a density of 100 gcm3 (physical property) These properties how-ever apply only to water at standard ldquoroomrdquo temperature and pressure At tem-peratures greater than 100degC water is a gas (physical property) with a densityof about 00006 gcm3 (physical property) that reacts rapidly with many dif-ferent substances (chemical property) As you can see the properties of waterare dramatically different under different conditions

States of MatterImagine you are sitting on a bench breathing heavily and drinking water aftera tiring game of soccer In this scenario you are in contact with three differentforms of matter the bench is a solid the water is a liquid and the air you breatheis a gas In fact all matter that exists on Earth can be classified as one of thesephysical forms called states of matter Scientists recognize a fourth state ofmatter called plasma but it does not occur naturally on Earth except in the formof lightning bolts The physical state of a substance is a physical property ofthat substance Each of the three common states of matter can be distinguishedby the way it fills a container

Solids A solid is a form of matter that has its own definite shape and vol-ume Wood iron paper and sugar are examples of solids The particles ofmatter in a solid are very tightly packed when heated a solid expands butonly slightly Because its shape is definite a solid may not conform to theshape of the container in which it is placed The tight packing of particles ina solid makes it incompressible that is it cannot be pressed into a smallervolume It is important to understand that a solid is not defined by its rigid-ity or hardness the marble statue in Figure 3-4 is rigid whereas wax sculp-ture is soft yet both are solids

Liquids A liquid is a form of matter that flows has constant volume andtakes the shape of its container Common examples of liquids include waterblood and mercury The particles in a liquid are not rigidly held in placeand are less closely packed than are the particles in a solid liquid particles

58 Chapter 3 MattermdashProperties and Changes

Figure 3-4

The properties of the solidmaterials marble and waxmake these sculptures possibleParticles in a solid are tightlypacked giving definite shapeand volume to the solid

c

ba

Solid

a b

c

Chem MC-058

null

17444711

31 Properties of Matter 59

Figure 3-5

Despite having differentshapes each of these measuringcups holds the same volume ofliquid

River water flows to fitwithin the boundaries of itsbanks regardless of the curvesalong its path

Molecules in a liquid areclosely packed but can still moverelatively freely

c

b

a

Liquid

a bc

Figure 3-6

Molecules in a gas are farapart and freely moving

Neon gas completely fills the tubes of the electricartwork

b

a

are able to move past each other This allows a liquid to flow and take theshape of its container although it may not completely fill the container Aliquidrsquos volume is constant regardless of the size and shape of the containerin which the liquid is held the volume of the liquid remains the same Thisis why measuring cups used in cooking such as those pictured in Figure3-5 can be made in a variety of shapes yet still measure the same volumeBecause of the way the particles of a liquid are packed liquids are virtu-ally incompressible Like solids liquids tend to expand when heated

Gases A gas is a form of matter that flows to conform to the shape of itscontainer and fills the entire volume of its container Examples of gasesinclude neon which is used in the lighted artwork in Figure 3-6 methanewhich is used in cooking and air which is a mixture of gases Compared tosolids and liquids the particles of gases are very far apart Because of the sig-nificant amount of space between particles gases are easily compressed Theproblem-solving LAB in this section poses several important questions aboutthe practical use of compressed gas

It is likely that you are familiar with the word vapor as it relates to theword gas The words gas and vapor while similar do not mean the samething and should not be used interchangeably The word gas refers to a sub-stance that is naturally in thegaseous state at room temperatureThe word vapor refers to thegaseous state of a substance that isa solid or a liquid at room tempera-ture For example steam is a vaporbecause at room temperature waterexists as a liquid

bGasa

Chem MC-059

null

11253363

60 Chapter 3 MattermdashProperties and Changes

Section 31 Assessment

1 Describe the characteristics that identify a sampleof matter as being a substance

2 Classify each of the following as a physical orchemical property

a Iron and oxygen form rustb Iron is more dense than aluminumc Magnesium burns brightly when ignitedd Oil and water do not mixe Mercury melts at 39degC

3 Create a table that describes the three commonstates of matter in terms of their shape volumeand compressibility

4 Thinking Critically Using what you know aboutthe compressibility of gases explain why the oxy-gen in a SCUBA tank is compressed

5 Interpreting Data Bromine is a reddish-brownliquid that boils at 59degC Bromine is highly reactivewith many metals For example it reacts withsodium to form a white solid Classify each of theseproperties of bromine as either a physical or achemical property

problem-solving LAB

How is compressed gasreleasedRecognizing Cause and Effect Tanks of com-pressed gases are a common sight in a chemistrylaboratory For example nitrogen is often flowedover a reaction in progress to displace othergases that might interfere with the experimentGiven what you know about the properties ofgases explain how compressed nitrogen isreleased

AnalysisBy definition the particles of gases are far apartand gases tend to fill their container even if thecontainer is a laboratory room Tanks of com-pressed gas come from the supplier capped toprevent the gas from escaping In the lab achemist or technician attaches a regulator to thetank and secures the tank to a stable fixture

Thinking Critically1 Explain why the flow of compressed gas must

be controlled for practical use

2 Predict what would happen if the valve on afull tank of compressed gas were suddenlyopened all the way or if the full tank werepunctured

The fact that substances can change form as in the example of waterchanging to steam is another important concept in chemistry If you reviewwhat you just learned about physical properties of substances you can seethat because the particular form of a substance is a physical property chang-ing the form introduces or adds another physical property to its list of char-acteristics In fact resources that provide tables of physical and chemicalproperties of substances such as the CRC Handbook of Chemistry and Physicsgenerally include the physical properties of substances in all of the states inwhich they can exist

chemistrymccomself_check_quiz

Chem MC-060

null

38870155

32 Changes in Matter 61

Objectivesbull Define physical change and

list several common physicalchanges

bull Define chemical change andlist several indications that achemical change has takenplace

bull Apply the law of conserva-tion of mass to chemicalreactions

Vocabularyphysical changechemical changelaw of conservation of mass

Section Changes in Matter

You learned in Section 31 that scientists can describe matter in terms of phys-ical and chemical properties For example a physical property of copperallows it to be drawn into copper wire and a chemical property of copperaccounts for the fact that when a solution of copper ions is combined withammonia the copper solution changes to a deep blue color The key conceptin both of these examples is that the substance copper changed in some wayIn this section yoursquoll explore how matter changes as a result of its physicaland chemical properties

Physical ChangesA substance often undergoes changes that result in a dramatically differentappearance yet leave the composition of the substance unchanged An exam-ple is the crumpling of a sheet of aluminum foil While the foil goes from asmooth flat mirrorlike sheet to a round compact ball the actual composi-tion of the foil is unchangedmdashit is still aluminum Changes such as this whichalter a substance without changing its composition are known as physicalchanges Cutting a sheet of paper and breaking a crystal are other examplesof physical changes in matter Can you name some other physical changesYour list might include verbs such as bend grind crumple split and crushall of which indicate physical change

As with other physical properties the state of matter depends on the tem-perature and pressure of the surroundings As temperature and pressurechange most substances undergo a change from one state (or phase) toanother For example at atmospheric pressure and at temperatures below0degC water is in its solid state which is known as ice As heat is added to theice it melts and becomes liquid water This change of state is a physicalchange because even though ice and water have very different appearancestheir composition is the same If the temperature of the water increases to100degC the water begins to boil and liquid water is converted to steam Meltingand formation of a gas are both physical changes and phase changes Figure3-7 shows condensation another common phase change When you encounterterms such as boil freeze condense vaporize or melt in your study of chem-istry the meaning generally refers to a phase change in matter

32

a

Figure 3-7

Condensation on an icy bev-erage glass is the result of thephase change of water ina gaseous state to water in aliquid state

The characteristic ldquofogrdquo ofdry ice is actually fine waterdroplets formed by condensa-tion of water vapor from the airsurrounding the very cold dryice Refer to Table C-1 inAppendix C for a key to atomcolor conventions

b

a

b

a b

LAB

See page 953 in Appendix E forComparing Frozen Liquids

Chem MC-061

null

15443536

CMC_Spn_C03-S02

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4174369

The temperature and pressure at which a substance undergoes a phasechange are important physical properties These properties are listed as themelting and boiling points of the substance Table 3-1 on page 56 providesthis information for several common substances Like density the meltingpoint and boiling point are intensive physical properties that may be used toidentify unknown substances For example if an unknown solid melts at801degC and boils at 1413degCmdashvery high temperaturesmdashit is most probablysodium chloride or common table salt Tables of intensive properties suchas those given in the CRC Handbook of Chemistry and Physics are indis-pensable tools in identifying unknown substances from experimental data

Chemical ChangesAs you learned earlier chemical properties relate to the ability of a substanceto combine with or change into one or more substances A process thatinvolves one or more substances changing into new substances is called achemical change which is commonly referred to as a chemical reaction Thenew substances formed in the reaction have different compositions and dif-ferent properties from the substances present before the reaction occurred Forexample the crushing of grapes that is part of the wine-making process is aphysical change but the fermentation of the juice sugars and other ingredi-ents to wine is a chemical change The Chemistry and Society feature at theend of the chapter describes some interesting consequences of physical andchemical changes in the production of concrete

Letrsquos consider again the rusting of iron When a freshly exposed iron surface is left in contact with air it slowly changes into a new substancenamely the rust shown in Figure 3-8a The iron reacts with oxygen in the airto form a new substance rust Rust is a chemical combination of iron and oxy-gen In chemical reactions the starting substances are called reactants and thenew substances that are formed are called products Thus iron and oxygen arereactants and rust is a product When you encounter terms such as exploderust oxidize corrode tarnish ferment burn or rot the meaning generallyrefers to a chemical reaction in which reactant substances produce differentproduct substances

62 Chapter 3 MattermdashProperties and Changes

a

Figure 3-8

The formation of a gas orsolid when reactants mix oftenindicates that a chemical reac-tion has taken place Rust is theresult of a chemical reaction

Color changes generallyindicate that a chemical reactionhas taken place One example isthe color change of tree leavesin the fall

b

a

b

Chem MC-062

null

14978511

Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

Chem MC-063

null

1447691

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

null

4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

null

14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

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20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

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16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

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10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 6: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

31 Properties of Matter 59

Figure 3-5

Despite having differentshapes each of these measuringcups holds the same volume ofliquid

River water flows to fitwithin the boundaries of itsbanks regardless of the curvesalong its path

Molecules in a liquid areclosely packed but can still moverelatively freely

c

b

a

Liquid

a bc

Figure 3-6

Molecules in a gas are farapart and freely moving

Neon gas completely fills the tubes of the electricartwork

b

a

are able to move past each other This allows a liquid to flow and take theshape of its container although it may not completely fill the container Aliquidrsquos volume is constant regardless of the size and shape of the containerin which the liquid is held the volume of the liquid remains the same Thisis why measuring cups used in cooking such as those pictured in Figure3-5 can be made in a variety of shapes yet still measure the same volumeBecause of the way the particles of a liquid are packed liquids are virtu-ally incompressible Like solids liquids tend to expand when heated

Gases A gas is a form of matter that flows to conform to the shape of itscontainer and fills the entire volume of its container Examples of gasesinclude neon which is used in the lighted artwork in Figure 3-6 methanewhich is used in cooking and air which is a mixture of gases Compared tosolids and liquids the particles of gases are very far apart Because of the sig-nificant amount of space between particles gases are easily compressed Theproblem-solving LAB in this section poses several important questions aboutthe practical use of compressed gas

It is likely that you are familiar with the word vapor as it relates to theword gas The words gas and vapor while similar do not mean the samething and should not be used interchangeably The word gas refers to a sub-stance that is naturally in thegaseous state at room temperatureThe word vapor refers to thegaseous state of a substance that isa solid or a liquid at room tempera-ture For example steam is a vaporbecause at room temperature waterexists as a liquid

bGasa

Chem MC-059

null

11253363

60 Chapter 3 MattermdashProperties and Changes

Section 31 Assessment

1 Describe the characteristics that identify a sampleof matter as being a substance

2 Classify each of the following as a physical orchemical property

a Iron and oxygen form rustb Iron is more dense than aluminumc Magnesium burns brightly when ignitedd Oil and water do not mixe Mercury melts at 39degC

3 Create a table that describes the three commonstates of matter in terms of their shape volumeand compressibility

4 Thinking Critically Using what you know aboutthe compressibility of gases explain why the oxy-gen in a SCUBA tank is compressed

5 Interpreting Data Bromine is a reddish-brownliquid that boils at 59degC Bromine is highly reactivewith many metals For example it reacts withsodium to form a white solid Classify each of theseproperties of bromine as either a physical or achemical property

problem-solving LAB

How is compressed gasreleasedRecognizing Cause and Effect Tanks of com-pressed gases are a common sight in a chemistrylaboratory For example nitrogen is often flowedover a reaction in progress to displace othergases that might interfere with the experimentGiven what you know about the properties ofgases explain how compressed nitrogen isreleased

AnalysisBy definition the particles of gases are far apartand gases tend to fill their container even if thecontainer is a laboratory room Tanks of com-pressed gas come from the supplier capped toprevent the gas from escaping In the lab achemist or technician attaches a regulator to thetank and secures the tank to a stable fixture

Thinking Critically1 Explain why the flow of compressed gas must

be controlled for practical use

2 Predict what would happen if the valve on afull tank of compressed gas were suddenlyopened all the way or if the full tank werepunctured

The fact that substances can change form as in the example of waterchanging to steam is another important concept in chemistry If you reviewwhat you just learned about physical properties of substances you can seethat because the particular form of a substance is a physical property chang-ing the form introduces or adds another physical property to its list of char-acteristics In fact resources that provide tables of physical and chemicalproperties of substances such as the CRC Handbook of Chemistry and Physicsgenerally include the physical properties of substances in all of the states inwhich they can exist

chemistrymccomself_check_quiz

Chem MC-060

null

38870155

32 Changes in Matter 61

Objectivesbull Define physical change and

list several common physicalchanges

bull Define chemical change andlist several indications that achemical change has takenplace

bull Apply the law of conserva-tion of mass to chemicalreactions

Vocabularyphysical changechemical changelaw of conservation of mass

Section Changes in Matter

You learned in Section 31 that scientists can describe matter in terms of phys-ical and chemical properties For example a physical property of copperallows it to be drawn into copper wire and a chemical property of copperaccounts for the fact that when a solution of copper ions is combined withammonia the copper solution changes to a deep blue color The key conceptin both of these examples is that the substance copper changed in some wayIn this section yoursquoll explore how matter changes as a result of its physicaland chemical properties

Physical ChangesA substance often undergoes changes that result in a dramatically differentappearance yet leave the composition of the substance unchanged An exam-ple is the crumpling of a sheet of aluminum foil While the foil goes from asmooth flat mirrorlike sheet to a round compact ball the actual composi-tion of the foil is unchangedmdashit is still aluminum Changes such as this whichalter a substance without changing its composition are known as physicalchanges Cutting a sheet of paper and breaking a crystal are other examplesof physical changes in matter Can you name some other physical changesYour list might include verbs such as bend grind crumple split and crushall of which indicate physical change

As with other physical properties the state of matter depends on the tem-perature and pressure of the surroundings As temperature and pressurechange most substances undergo a change from one state (or phase) toanother For example at atmospheric pressure and at temperatures below0degC water is in its solid state which is known as ice As heat is added to theice it melts and becomes liquid water This change of state is a physicalchange because even though ice and water have very different appearancestheir composition is the same If the temperature of the water increases to100degC the water begins to boil and liquid water is converted to steam Meltingand formation of a gas are both physical changes and phase changes Figure3-7 shows condensation another common phase change When you encounterterms such as boil freeze condense vaporize or melt in your study of chem-istry the meaning generally refers to a phase change in matter

32

a

Figure 3-7

Condensation on an icy bev-erage glass is the result of thephase change of water ina gaseous state to water in aliquid state

The characteristic ldquofogrdquo ofdry ice is actually fine waterdroplets formed by condensa-tion of water vapor from the airsurrounding the very cold dryice Refer to Table C-1 inAppendix C for a key to atomcolor conventions

b

a

b

a b

LAB

See page 953 in Appendix E forComparing Frozen Liquids

Chem MC-061

null

15443536

CMC_Spn_C03-S02

null

4174369

The temperature and pressure at which a substance undergoes a phasechange are important physical properties These properties are listed as themelting and boiling points of the substance Table 3-1 on page 56 providesthis information for several common substances Like density the meltingpoint and boiling point are intensive physical properties that may be used toidentify unknown substances For example if an unknown solid melts at801degC and boils at 1413degCmdashvery high temperaturesmdashit is most probablysodium chloride or common table salt Tables of intensive properties suchas those given in the CRC Handbook of Chemistry and Physics are indis-pensable tools in identifying unknown substances from experimental data

Chemical ChangesAs you learned earlier chemical properties relate to the ability of a substanceto combine with or change into one or more substances A process thatinvolves one or more substances changing into new substances is called achemical change which is commonly referred to as a chemical reaction Thenew substances formed in the reaction have different compositions and dif-ferent properties from the substances present before the reaction occurred Forexample the crushing of grapes that is part of the wine-making process is aphysical change but the fermentation of the juice sugars and other ingredi-ents to wine is a chemical change The Chemistry and Society feature at theend of the chapter describes some interesting consequences of physical andchemical changes in the production of concrete

Letrsquos consider again the rusting of iron When a freshly exposed iron surface is left in contact with air it slowly changes into a new substancenamely the rust shown in Figure 3-8a The iron reacts with oxygen in the airto form a new substance rust Rust is a chemical combination of iron and oxy-gen In chemical reactions the starting substances are called reactants and thenew substances that are formed are called products Thus iron and oxygen arereactants and rust is a product When you encounter terms such as exploderust oxidize corrode tarnish ferment burn or rot the meaning generallyrefers to a chemical reaction in which reactant substances produce differentproduct substances

62 Chapter 3 MattermdashProperties and Changes

a

Figure 3-8

The formation of a gas orsolid when reactants mix oftenindicates that a chemical reac-tion has taken place Rust is theresult of a chemical reaction

Color changes generallyindicate that a chemical reactionhas taken place One example isthe color change of tree leavesin the fall

b

a

b

Chem MC-062

null

14978511

Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

Chem MC-063

null

1447691

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

null

4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

null

14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

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7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

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10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

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20846185

CMC_Spn_C03-S04

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10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

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16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

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10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 7: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

60 Chapter 3 MattermdashProperties and Changes

Section 31 Assessment

1 Describe the characteristics that identify a sampleof matter as being a substance

2 Classify each of the following as a physical orchemical property

a Iron and oxygen form rustb Iron is more dense than aluminumc Magnesium burns brightly when ignitedd Oil and water do not mixe Mercury melts at 39degC

3 Create a table that describes the three commonstates of matter in terms of their shape volumeand compressibility

4 Thinking Critically Using what you know aboutthe compressibility of gases explain why the oxy-gen in a SCUBA tank is compressed

5 Interpreting Data Bromine is a reddish-brownliquid that boils at 59degC Bromine is highly reactivewith many metals For example it reacts withsodium to form a white solid Classify each of theseproperties of bromine as either a physical or achemical property

problem-solving LAB

How is compressed gasreleasedRecognizing Cause and Effect Tanks of com-pressed gases are a common sight in a chemistrylaboratory For example nitrogen is often flowedover a reaction in progress to displace othergases that might interfere with the experimentGiven what you know about the properties ofgases explain how compressed nitrogen isreleased

AnalysisBy definition the particles of gases are far apartand gases tend to fill their container even if thecontainer is a laboratory room Tanks of com-pressed gas come from the supplier capped toprevent the gas from escaping In the lab achemist or technician attaches a regulator to thetank and secures the tank to a stable fixture

Thinking Critically1 Explain why the flow of compressed gas must

be controlled for practical use

2 Predict what would happen if the valve on afull tank of compressed gas were suddenlyopened all the way or if the full tank werepunctured

The fact that substances can change form as in the example of waterchanging to steam is another important concept in chemistry If you reviewwhat you just learned about physical properties of substances you can seethat because the particular form of a substance is a physical property chang-ing the form introduces or adds another physical property to its list of char-acteristics In fact resources that provide tables of physical and chemicalproperties of substances such as the CRC Handbook of Chemistry and Physicsgenerally include the physical properties of substances in all of the states inwhich they can exist

chemistrymccomself_check_quiz

Chem MC-060

null

38870155

32 Changes in Matter 61

Objectivesbull Define physical change and

list several common physicalchanges

bull Define chemical change andlist several indications that achemical change has takenplace

bull Apply the law of conserva-tion of mass to chemicalreactions

Vocabularyphysical changechemical changelaw of conservation of mass

Section Changes in Matter

You learned in Section 31 that scientists can describe matter in terms of phys-ical and chemical properties For example a physical property of copperallows it to be drawn into copper wire and a chemical property of copperaccounts for the fact that when a solution of copper ions is combined withammonia the copper solution changes to a deep blue color The key conceptin both of these examples is that the substance copper changed in some wayIn this section yoursquoll explore how matter changes as a result of its physicaland chemical properties

Physical ChangesA substance often undergoes changes that result in a dramatically differentappearance yet leave the composition of the substance unchanged An exam-ple is the crumpling of a sheet of aluminum foil While the foil goes from asmooth flat mirrorlike sheet to a round compact ball the actual composi-tion of the foil is unchangedmdashit is still aluminum Changes such as this whichalter a substance without changing its composition are known as physicalchanges Cutting a sheet of paper and breaking a crystal are other examplesof physical changes in matter Can you name some other physical changesYour list might include verbs such as bend grind crumple split and crushall of which indicate physical change

As with other physical properties the state of matter depends on the tem-perature and pressure of the surroundings As temperature and pressurechange most substances undergo a change from one state (or phase) toanother For example at atmospheric pressure and at temperatures below0degC water is in its solid state which is known as ice As heat is added to theice it melts and becomes liquid water This change of state is a physicalchange because even though ice and water have very different appearancestheir composition is the same If the temperature of the water increases to100degC the water begins to boil and liquid water is converted to steam Meltingand formation of a gas are both physical changes and phase changes Figure3-7 shows condensation another common phase change When you encounterterms such as boil freeze condense vaporize or melt in your study of chem-istry the meaning generally refers to a phase change in matter

32

a

Figure 3-7

Condensation on an icy bev-erage glass is the result of thephase change of water ina gaseous state to water in aliquid state

The characteristic ldquofogrdquo ofdry ice is actually fine waterdroplets formed by condensa-tion of water vapor from the airsurrounding the very cold dryice Refer to Table C-1 inAppendix C for a key to atomcolor conventions

b

a

b

a b

LAB

See page 953 in Appendix E forComparing Frozen Liquids

Chem MC-061

null

15443536

CMC_Spn_C03-S02

null

4174369

The temperature and pressure at which a substance undergoes a phasechange are important physical properties These properties are listed as themelting and boiling points of the substance Table 3-1 on page 56 providesthis information for several common substances Like density the meltingpoint and boiling point are intensive physical properties that may be used toidentify unknown substances For example if an unknown solid melts at801degC and boils at 1413degCmdashvery high temperaturesmdashit is most probablysodium chloride or common table salt Tables of intensive properties suchas those given in the CRC Handbook of Chemistry and Physics are indis-pensable tools in identifying unknown substances from experimental data

Chemical ChangesAs you learned earlier chemical properties relate to the ability of a substanceto combine with or change into one or more substances A process thatinvolves one or more substances changing into new substances is called achemical change which is commonly referred to as a chemical reaction Thenew substances formed in the reaction have different compositions and dif-ferent properties from the substances present before the reaction occurred Forexample the crushing of grapes that is part of the wine-making process is aphysical change but the fermentation of the juice sugars and other ingredi-ents to wine is a chemical change The Chemistry and Society feature at theend of the chapter describes some interesting consequences of physical andchemical changes in the production of concrete

Letrsquos consider again the rusting of iron When a freshly exposed iron surface is left in contact with air it slowly changes into a new substancenamely the rust shown in Figure 3-8a The iron reacts with oxygen in the airto form a new substance rust Rust is a chemical combination of iron and oxy-gen In chemical reactions the starting substances are called reactants and thenew substances that are formed are called products Thus iron and oxygen arereactants and rust is a product When you encounter terms such as exploderust oxidize corrode tarnish ferment burn or rot the meaning generallyrefers to a chemical reaction in which reactant substances produce differentproduct substances

62 Chapter 3 MattermdashProperties and Changes

a

Figure 3-8

The formation of a gas orsolid when reactants mix oftenindicates that a chemical reac-tion has taken place Rust is theresult of a chemical reaction

Color changes generallyindicate that a chemical reactionhas taken place One example isthe color change of tree leavesin the fall

b

a

b

Chem MC-062

null

14978511

Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

Chem MC-063

null

1447691

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

null

4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

null

14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

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20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

null

16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 8: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

32 Changes in Matter 61

Objectivesbull Define physical change and

list several common physicalchanges

bull Define chemical change andlist several indications that achemical change has takenplace

bull Apply the law of conserva-tion of mass to chemicalreactions

Vocabularyphysical changechemical changelaw of conservation of mass

Section Changes in Matter

You learned in Section 31 that scientists can describe matter in terms of phys-ical and chemical properties For example a physical property of copperallows it to be drawn into copper wire and a chemical property of copperaccounts for the fact that when a solution of copper ions is combined withammonia the copper solution changes to a deep blue color The key conceptin both of these examples is that the substance copper changed in some wayIn this section yoursquoll explore how matter changes as a result of its physicaland chemical properties

Physical ChangesA substance often undergoes changes that result in a dramatically differentappearance yet leave the composition of the substance unchanged An exam-ple is the crumpling of a sheet of aluminum foil While the foil goes from asmooth flat mirrorlike sheet to a round compact ball the actual composi-tion of the foil is unchangedmdashit is still aluminum Changes such as this whichalter a substance without changing its composition are known as physicalchanges Cutting a sheet of paper and breaking a crystal are other examplesof physical changes in matter Can you name some other physical changesYour list might include verbs such as bend grind crumple split and crushall of which indicate physical change

As with other physical properties the state of matter depends on the tem-perature and pressure of the surroundings As temperature and pressurechange most substances undergo a change from one state (or phase) toanother For example at atmospheric pressure and at temperatures below0degC water is in its solid state which is known as ice As heat is added to theice it melts and becomes liquid water This change of state is a physicalchange because even though ice and water have very different appearancestheir composition is the same If the temperature of the water increases to100degC the water begins to boil and liquid water is converted to steam Meltingand formation of a gas are both physical changes and phase changes Figure3-7 shows condensation another common phase change When you encounterterms such as boil freeze condense vaporize or melt in your study of chem-istry the meaning generally refers to a phase change in matter

32

a

Figure 3-7

Condensation on an icy bev-erage glass is the result of thephase change of water ina gaseous state to water in aliquid state

The characteristic ldquofogrdquo ofdry ice is actually fine waterdroplets formed by condensa-tion of water vapor from the airsurrounding the very cold dryice Refer to Table C-1 inAppendix C for a key to atomcolor conventions

b

a

b

a b

LAB

See page 953 in Appendix E forComparing Frozen Liquids

Chem MC-061

null

15443536

CMC_Spn_C03-S02

null

4174369

The temperature and pressure at which a substance undergoes a phasechange are important physical properties These properties are listed as themelting and boiling points of the substance Table 3-1 on page 56 providesthis information for several common substances Like density the meltingpoint and boiling point are intensive physical properties that may be used toidentify unknown substances For example if an unknown solid melts at801degC and boils at 1413degCmdashvery high temperaturesmdashit is most probablysodium chloride or common table salt Tables of intensive properties suchas those given in the CRC Handbook of Chemistry and Physics are indis-pensable tools in identifying unknown substances from experimental data

Chemical ChangesAs you learned earlier chemical properties relate to the ability of a substanceto combine with or change into one or more substances A process thatinvolves one or more substances changing into new substances is called achemical change which is commonly referred to as a chemical reaction Thenew substances formed in the reaction have different compositions and dif-ferent properties from the substances present before the reaction occurred Forexample the crushing of grapes that is part of the wine-making process is aphysical change but the fermentation of the juice sugars and other ingredi-ents to wine is a chemical change The Chemistry and Society feature at theend of the chapter describes some interesting consequences of physical andchemical changes in the production of concrete

Letrsquos consider again the rusting of iron When a freshly exposed iron surface is left in contact with air it slowly changes into a new substancenamely the rust shown in Figure 3-8a The iron reacts with oxygen in the airto form a new substance rust Rust is a chemical combination of iron and oxy-gen In chemical reactions the starting substances are called reactants and thenew substances that are formed are called products Thus iron and oxygen arereactants and rust is a product When you encounter terms such as exploderust oxidize corrode tarnish ferment burn or rot the meaning generallyrefers to a chemical reaction in which reactant substances produce differentproduct substances

62 Chapter 3 MattermdashProperties and Changes

a

Figure 3-8

The formation of a gas orsolid when reactants mix oftenindicates that a chemical reac-tion has taken place Rust is theresult of a chemical reaction

Color changes generallyindicate that a chemical reactionhas taken place One example isthe color change of tree leavesin the fall

b

a

b

Chem MC-062

null

14978511

Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

Chem MC-063

null

1447691

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

null

4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

null

14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

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7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

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20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

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16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 9: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

The temperature and pressure at which a substance undergoes a phasechange are important physical properties These properties are listed as themelting and boiling points of the substance Table 3-1 on page 56 providesthis information for several common substances Like density the meltingpoint and boiling point are intensive physical properties that may be used toidentify unknown substances For example if an unknown solid melts at801degC and boils at 1413degCmdashvery high temperaturesmdashit is most probablysodium chloride or common table salt Tables of intensive properties suchas those given in the CRC Handbook of Chemistry and Physics are indis-pensable tools in identifying unknown substances from experimental data

Chemical ChangesAs you learned earlier chemical properties relate to the ability of a substanceto combine with or change into one or more substances A process thatinvolves one or more substances changing into new substances is called achemical change which is commonly referred to as a chemical reaction Thenew substances formed in the reaction have different compositions and dif-ferent properties from the substances present before the reaction occurred Forexample the crushing of grapes that is part of the wine-making process is aphysical change but the fermentation of the juice sugars and other ingredi-ents to wine is a chemical change The Chemistry and Society feature at theend of the chapter describes some interesting consequences of physical andchemical changes in the production of concrete

Letrsquos consider again the rusting of iron When a freshly exposed iron surface is left in contact with air it slowly changes into a new substancenamely the rust shown in Figure 3-8a The iron reacts with oxygen in the airto form a new substance rust Rust is a chemical combination of iron and oxy-gen In chemical reactions the starting substances are called reactants and thenew substances that are formed are called products Thus iron and oxygen arereactants and rust is a product When you encounter terms such as exploderust oxidize corrode tarnish ferment burn or rot the meaning generallyrefers to a chemical reaction in which reactant substances produce differentproduct substances

62 Chapter 3 MattermdashProperties and Changes

a

Figure 3-8

The formation of a gas orsolid when reactants mix oftenindicates that a chemical reac-tion has taken place Rust is theresult of a chemical reaction

Color changes generallyindicate that a chemical reactionhas taken place One example isthe color change of tree leavesin the fall

b

a

b

Chem MC-062

null

14978511

Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

Chem MC-063

null

1447691

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

null

4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

null

14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

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16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

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10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 10: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Evidence of a chemical reaction As Figure 3-8a shows rust is a brown-ish-orange powdery substance that looks very different from iron and oxygenRust is not attracted to a magnet whereas iron is The observation that the prod-uct (rust) has different properties than the reactants (iron and oxygen) is evi-dence that a chemical reaction has taken place A chemical reaction alwaysproduces a change in properties Figures 3-8 and 3-9 illustrate several com-mon indicators of chemical change The CHEMLAB at the end of the chap-ter provides a practical laboratory experience with chemical reactions

Conservation of MassAlthough chemical reactions have been observed over the course of humanhistory it was only in the late eighteenth century that scientists began to usequantitative tools to monitor chemical changes The revolutionary quantita-tive tool developed at this time was the analytical balance which was capa-ble of measuring very small changes in mass

By carefully measuring mass before and after many chemical reactions itwas observed that although chemical changes occurred the total massinvolved in the reaction remained constant The constancy of mass in chem-ical reactions was observed so often that scientists assumed the phenomenonmust be true for all reactions They summarized this observation in a scien-tific law The law of conservation of mass states that mass is neither creatednor destroyed during a chemical reactionmdashit is conserved This law was oneof the great achievements of eighteenth-century science The equation formof the law of conservation of mass is

Massreactants Massproducts

The French scientist Antoine Lavoisier (1743ndash1794) was one of the firstto use an analytical balance like the one shown in Figure 3-10 to monitorchemical reactions He studied the thermal decomposition of mercury(II)oxide known then as calx of mercury Mercury(II) oxide is a powderyred solid When it is heated the red solid reacts to form silvery liquidmercury and colorless oxygen gas as shown in Figure 3-11 on the nextpage The color change and production of a gas are indicators of a

32 Changes in Matter 63

Figure 3-9

Energy changes indicatechemical reactions For examplethe burning of wood is a com-mon example of a reaction thatreleases heat

The change in the smell of asubstance or the production ofan odor may be an indication ofa chemical reaction

b

a

a b

Figure 3-10

The development of scientifictools such as this analytical bal-ance gave a degree of precisionto measurements that greatlyimproved general scientificunderstanding

Chem MC-063

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1447691

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

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4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

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14105936

CMC_Spn_C03-S03

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3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

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17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

null

16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 11: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

64 Chapter 3 MattermdashProperties and Changes

chemical reaction When the reaction is performed in a closed container theoxygen gas cannot escape and the mass before and after the reaction can bemeasured The masses will be the same

Mercury(II) oxide yields mercury oxygen2 HgO rarr 2 Hg + O2

A more modern digital analytical balance can be used to prove the conser-vation of mass of this example The law of conservation of mass is one of themost fundamental concepts of chemistry Letrsquos examine more closely somesituations that illustrate the concept Example Problem 3-1 leads you througha sample calculation The practice problems also illustrate the law of con-servation of mass

200 g 16 gmass of products

216 gMass of reactant

EXAMPLE PROBLEM 3-1

Mercury occurs naturally in airwater soil and living organismsSeafood that is intended forhuman consumption is monitoredto ensure that the products donot contain levels of mercuryexceeding the established limitsfor public safety

Figure 3-11

Lavoisierrsquos experimental decom-position of mercury(II) oxide isone proof of the law of conser-vation of mass Although achemical reaction is obvious(powder to liquid mercury) mat-ter was neither created nordestroyed

Conservation of MassIn an experiment 1000 g of red mercury(II) oxide powder is placedin an open flask and heated until it is converted to liquid mercuryand oxygen gas The liquid mercury has a mass of 926 g What isthe mass of oxygen formed in the reaction

1 Analyze the ProblemYou are given the mass of a reactant and the mass of one of theproducts in a chemical reaction Applying the law of conserva-tion of mass the total mass of the products must equal the totalmass of the reactants This means that the mass of the liquidmercury plus the mass of the oxygen gas must equal the mass ofthe mercury(II) oxide powder

Known Unknown

Mass of mercury(II) oxide Mass of oxygen formed 1000 g gMass of liquid mercury 926 g

Chem MC-064

null

4346781

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

null

14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

null

16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 12: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

32 Changes in Matter 65

PRACTICE PROBLEMS6 From a laboratory process designed to separate water into hydrogen

and oxygen gas a student collected 100 g of hydrogen and 794 g ofoxygen How much water was originally involved in the process

7 A student carefully placed 156 g of sodium in a reactor supplied withan excess quantity of chlorine gas When the reaction was completethe student obtained 397 g of sodium chloride How many grams ofchlorine gas reacted How many grams of sodium reacted

8 In a flask 103 g of aluminum reacted with 1000 g of liquid bromineto form aluminum bromide After the reaction no aluminumremained and 85 grams of bromine remained unreacted How manygrams of bromine reacted How many grams of compound wereformed

9 A 100-g sample of magnesium reacts with oxygen to form 166 g ofmagnesium oxide How many grams of oxygen reacted

Section 32 Assessment

10 Describe the results of a physical change and listthree examples of physical change

11 Describe the results of a chemical change Listfour indicators of chemical change

12 Solve each of the following

a In the complete reaction of 2299 g of sodiumwith 3545 g of chlorine what mass of sodiumchloride is formed

b A 122-g sample of X reacts with a sample ofY to form 789 g of XY What is the mass of Ythat reacted

13 Thinking Critically A friend tells you ldquoBecausecomposition does not change during a physicalchange the appearance of a substance does notchangerdquo Is your friend correct Explain why

14 Classifying Classify each of the following ex-amples as a physical change or a chemical change

a crushing an aluminum canb recycling used aluminum cans to make new

aluminum cansc aluminum combining with oxygen to form alu-

minum oxide

For more practice withconservation of massgo to SupplementalPractice Problems in

Appendix A

Practice

2 Solve for the UnknownWrite an equation showing conservation of mass of reactants andproducts

Massreactants Massproducts

Massmercury(II) oxide Massmercury Massoxygen

Solve the equation for Massoxygen

Massoxygen Massmercury(II) oxide Massmercury

Substitute known values and solve

Massoxygen 1000 g 926 g

Massoxygen 074 g

3 Evaluate the AnswerThe sum of the masses of the two products equals the mass of thereactant verifying that mass has been conserved The answer is cor-rectly expressed to the hundredths place

chemistrymccomself_check_quiz

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

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14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

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17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

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7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

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10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

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20846185

CMC_Spn_C03-S04

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10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

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16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 13: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

66 Chapter 3 MattermdashProperties and Changes

Section 33 Mixtures of Matter

Objectivesbull Contrast mixtures and

substances

bull Classify mixtures as homo-geneous or heterogeneous

bull List and describe severaltechniques used to separatemixtures

Vocabularymixtureheterogeneous mixturehomogeneous mixturesolutionfiltrationdistillationcrystallizationchromatography

When scientists speak of the composition of matter they are referring to thekinds and amounts of components of which the matter is made On the basisof composition alone all matter can be classified into two broad categoriessubstances or mixtures You have already learned that a pure substance is aform of matter with a uniform and unchanging composition You also knowthat the intensive properties of pure substances do not change regardless ofthe physical state or amount of the substance But what is the result when twoor more substances are combined

MixturesA mixture is a combination of two or more pure substances in which eachpure substance retains its individual chemical properties The composition ofmixtures is variable and the number of mixtures that can be created by com-bining substances is infinite Although much of the focus of chemistry is thebehavior of substances it is important to remember that most everyday mat-ter occurs as mixtures Substances tend naturally to mix it is difficult to keepthings pure

Two mixtures sand and water and table salt and water are shown inFigure 3-12a You know water to be a colorless liquid Sand is a grainy solidthat does not dissolve in water When sand and water are mixed the twosubstances are in contact yet each substance retains its properties Thesand and water have not reacted Just by looking at the sandndashwater mixturein beaker A it is easy to see each separate substance Some mixtures how-ever may not look like mixtures at all The mixture of table salt and waterin the beaker labeled B is colorless and appears the same as pure water Howcan you determine if it is a mixture If you were to boil away the wateryou would see a white residue That residue shown in Figure 13-12b isthe salt Thus the colorless mixture actually contained two separate sub-stances The salt and the water physically mixed but did not react and wereseparated by the physical method of boiling

Figure 3-12

The components of the sandand water mixture (left) areobvious whereas the compo-nents of the table salt and watermixture (right) are not

The salt component becomesobvious when the mixture isboiled

b

a

a b

Chem MC-066

null

14105936

CMC_Spn_C03-S03

null

3108555

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

null

17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

null

7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

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10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

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16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

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10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 14: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Types of mixtures The combinations of pure substances shown inFigure 3-12 are indeed both mixtures despite their obvious visual differencesCan you think of some way to further define mixtures Mixtures themselvesare classified as either heterogeneous or homogeneous A heterogeneousmixture is one that does not blend smoothly throughout and in which the indi-vidual substances remain distinct The sand and water mixture is an exampleof a heterogeneous mixture Suppose you draw a drop from the top of the mix-ture using an eyedropper The drop would be almost completely water If youdraw a second drop from the bottom of the mixture that drop would containmostly sand Thus the composition of the sandndashwater mixture is not uniformmdashthe substances have not blended smoothly and the two substances of the mix-ture (sand on the bottom and water on the top) remain distinct In anotherexample fresh-squeezed orange juice is a mixture of juice and pulp The pulpcomponent floats on top of the juice component Is your favorite pizza a mix-ture The answer is yes when you consider that the pizza is a combination ofdistinct areas of dough sauce cheese and toppings We can therefore say thatthe existence of two or more distinct areas indicates a heterogeneous mixture

A homogeneous mixture has constant composition throughout it alwayshas a single phase Letrsquos examine the saltndashwater mixture using the eyedrop-per A drop of the mixture from the top of the beaker has the same composi-tion as a drop from the bottom of the beaker In fact every drop of the mixturecontains the same relative amounts of salt and water

Homogeneous mixtures are also referred to as solutions You are proba-bly most familiar with solutions in a liquid form such as cough suppressantmedicine and lemonade but solutions may contain solids liquids or gasesTable 3-3 lists the various types of solution systems and gives an example ofeach Solutions are very important in chemistry and in fact this textbookdevotes an entire chapter to the study of solutions

The solidndashsolid solution known as steel is called an alloy An alloy is ahomogeneous mixture of metals or a mixture of a metal and a nonmetal inwhich the metal substance is the major component The US Mintrsquos goldendollar coin shown in Figure 3-13 uses a metal alloy composed of 77 cop-per 12 zinc 7 manganese and 4 nickel surrounding a copper coreAlloys are also used in spacecraft and automobiles What might be the ben-efit of using alloys for these applications Manufacturers combine the prop-erties of various metals in an alloy to achieve greater strength and durabilityof their products

33 Mixtures of Matter 67

Types of Solution Systems

System Example

Gasndashgas Air is primarily a mixture of nitrogen oxygen and argongases

Gasndashliquid Carbonated beverages contain carbon dioxide gas in solution

Liquidndashgas Moist air contains water droplets in air (which is a mixture ofgases)

Liquidndashliquid Vinegar contains acetic acid in water

Solidndashliquid Sweetened powder drink contains sugar and other solidingredients in water

Solidndashsolid Steel is an alloy of iron containing carbon

Table 3-3

Figure 3-13

Coins issued by the US Mint are metal alloys The combina-tion of multiple metals gives thecoins specific properties such ascolor weight and durability

Chem MC-067

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17554436

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

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7988226

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

null

10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

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20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

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16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 15: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Separating MixturesMost matter exists naturally as mixtures For students and scientists to gain athorough understanding of matter it is very important to be able to do the reverseof mixing that is to separate mixtures into their component substances Becausethe substances in a mixture are physically combined the processes used to sep-arate a mixture are physical processes that are based on the difference in phys-ical properties of the substances Sometimes it is very easy to separate a mixtureseparating a mixture of pennies and nickels is not a difficult task More difficultwould be separating a mixture of sand and iron filings Or would it be Thedemonstration illustrated in Figure 3-14 shows how the sandndashiron mixture iseasily separated on the basis of the unique physical properties of the substancesinvolved Numerous techniques have been developed that take advantage of dif-ferent physical properties in order to separate mixtures

Heterogeneous mixtures composed of solids and liquids are easily separatedby filtration Filtration is a technique that uses a porous barrier to separate asolid from a liquid As Figure 3-15 shows the mixture is poured through apiece of filter paper that has been folded into a cone shape The liquid passesthrough leaving the solids trapped in the filter paper

68 Chapter 3 MattermdashProperties and Changes

Figure 3-14

The physical properties of theiron filings on the plate allowthem to be easily separatedfrom the sand using a magnet

Separating Ink DyesApplying Concepts Chromatography is animportant diagnostic tool for chemists Manytypes of substances can be separated and ana-lyzed using this technique In this experiment youwill use paper chromatography to separate thedyes in water-soluble black ink

Materials 9-oz wide-mouth plastic cups (2)round filter paper 1frasl4 piece of 11-cm round filterpaper scissors pointed object approximately 3ndash4mm diameter water-soluble black felt pen ormarker

Procedure 1 Fill one of the wide-mouth plastic cups with

water to about 2 cm from the top Wipe offany water drops on the lip of the cup

2 Place the round filter paper on a clean drysurface Make a concentrated ink spot in thecenter of the paper by firmly pressing the tipof the pen or marker onto the paper

3 Use a sharp object to create a small holeapproximately 3ndash4 mm or about the diameterof a pen tip in the center of the ink spot

4 Roll the 14 piece of filter paper into a tightcone This will act as a wick to draw the inkWork the pointed end of the wick into thehole in the center of the round filter paper

5 Place the paperwick apparatus on top of thecup of water with the wick in the water The

water will move up the wick and outwardthrough the round paper

6 When the water has moved to within about1 cm of the edge of the paper (about 20 min-utes) carefully remove the paper from thewater-filled cup and put it on the empty cup

Analysis1 Make a drawing of the round filter paper and

label the color bands How many distinct dyescan you identify

2 Why do you see different colors at differentlocations on the filter paper

3 How does your chromatogram compare withthose of your classmates who used other typesof black felt pens or markers Explain the differences

miniLAB

Chem MC-068

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Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

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70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

null

16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
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                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
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Page 16: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Most homogeneous mixtures can be separated by distillation Distillationis a separation technique that is based on differences in the boiling points ofthe substances involved In distillation a mixture is heated until the substancewith the lowest boiling point boils to a vapor that can then be condensed intoa liquid and collected When precisely controlled distillation can separate sub-stances having boiling points that differ by only a few degrees

Did you ever make rock candy as a child Making rock candy from a sugarsolution is an example of separation by crystallization Crystallization is a sep-aration technique that results in the formation of pure solid particles of a sub-stance from a solution containing the dissolved substance When the solutioncontains as much dissolved substance as it can possibly hold the addition ofa tiny amount more often causes the dissolved substance to come out of solu-tion and collect as crystals on some available surface In the rock candy exam-ple as water evaporates from the sugarndashwater solution the sugar is left behindas a solid crystal on the string Crystallization produces highly pure solids

Chromatography is a technique that separates the components of a mix-ture (called the mobile phase) on the basis of the tendency of each to travelor be drawn across the surface of another material (called the stationaryphase) The miniLAB in this section describes how you can separate a solu-tion such as ink into its components as it spreads across a stationary piece ofpaper The separation occurs because the various components of the inkspread through the paper at different rates

33 Mixtures of Matter 69

Figure 3-15

Filtration is a common techniqueused to remove impurities fromdrinking water Clean waterpasses through the porous filter

leaving behind the impuritiesthat can be easily discarded ba

Section 33 Assessment

15 How do mixtures and substances differ

16 Consider a mixture of water sand and oil Howmany phases are present How could you separatethis mixture into individual substances

17 Classify each of the following as either a hetero-geneous or homogeneous mixture

a orange juiceb tap waterc steel (a blend of iron and carbon)d aire raisin muffin

18 Thinking Critically When 50 mL of ethanol ismixed with 50 mL of water a solution forms Thevolume of the final solution is less than 100 mLPropose an explanation for this phenomenon(Hint Consider what you know about the spacebetween particles in liquids)

19 Applying Concepts Describe the separationtechnique that could be used to separate each ofthe following mixtures

a two colorless liquidsb a nondissolving solid mixed with a liquidc red and blue marbles of same size and mass

a b

chemistrymccomself_check_quiz

Topic MixturesTo learn more about mixturesand separation techniquesvisit the Chemistry Web siteat chemistrymccomActivity Use your research tomake a poster showing sev-eral real-life mixtures theiruses and techniques thatmight be used to separateeach mixture

Chem MC-069

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10365246

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

null

16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 17: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

70 Chapter 3 MattermdashProperties and Changes

Section 34 Elements and Compounds

Objectivesbull Distinguish between ele-

ments and compounds

bull Describe the organizationof elements on the periodictable

bull Explain how all compoundsobey the laws of definiteand multiple proportions

Vocabularyelementperiodic tablecompoundlaw of definite proportionspercent by masslaw of multiple proportions

To this point yoursquove examined many of the properties of matter Yoursquove alsolearned how scientists have organized classified and described matter byarranging it into various subcategories of components But there remainsanother fundamental level of classification of matter the classification of puresubstances as elements or compounds

ElementsRecall that earlier in this chapter you considered the diversity of your sur-roundings in terms of matter Although the diversity is astounding in realityall matter can be broken down into a relatively small number of basic build-ing blocks called elements An element is a pure substance that cannot beseparated into simpler substances by physical or chemical means On Earth91 elements occur naturally Copper oxygen and gold are examples of nat-urally occurring elements There are also several elements that do not existnaturally but have been developed by scientists

Each element has a unique chemical name and symbol The chemical sym-bol consists of one two or three letters the first letter is always capitalizedand the remaining letter(s) are always lowercase Why has so much effort beengiven to naming the elements The names and symbols of the elements areuniversally accepted by scientists in order to make the communication ofchemical information possible

The 91 naturally occurring elements are not equally abundant For exam-ple hydrogen is estimated to make up approximately 75 of the mass of theuniverse Oxygen and silicon together comprise almost 75 of the mass ofEarthrsquos crust while oxygen carbon and hydrogen account for more than 90of the human body Francium on the other hand is one of the least abundantnaturally occurring elements It is estimated that there is probably less than20 grams of francium dispersed throughout Earthrsquos crust To put that into per-spective the total mass of francium is approximately equal to the mass of yourpencil or pen

A first look at the periodic table As many new elements werebeing discovered in the early nineteenth century chemists began to seepatterns of similarities in the chemical and physical properties of par-ticular sets of elements Several schemes for organizing the elementson the basis of these similarities were proposed with varying degreesof success In 1869 the Russian chemist Dmitri Mendeleev made asignificant contribution to the effort Mendeleev devised the chartshown in Figure 3-16 which organized all of the elements that wereknown at the time into rows and columns based on their similaritiesand their masses Mendeleevrsquos organizational table was the first ver-sion of what has been further developed into the periodic table of ele-ments The periodic table organizes the elements into a grid ofhorizontal rows called periods and vertical columns called groups orfamilies Elements in the same group have similar chemical and phys-ical properties The table is called ldquoperiodicrdquo because the pattern ofsimilar properties repeats as you move from period to period

One of the brilliant aspects of Mendeleevrsquos original table was thatits structure could accommodate elements that were not known at

Figure 3-16

Although many early scientistshave contributed to the modernorganization of the elementsMendeleevrsquos system of rows andcolumns was a revolutionaryadvancement

Chem MC-070

null

20846185

CMC_Spn_C03-S04

null

10260762

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

null

16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 18: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Heterogeneousmixtures

dirt bloodmilk

lemonade gasolinesteel

oxygen goldiron

salt baking sodasugar

Homogeneousmixtures Elements Compounds

Matter

Mixtures

Physicalchanges

Chemicalchanges

Pure substances

the time Notice the blank spots in Mendeleevrsquos table By analyzing the sim-ilarities among the elements and their pattern of repetition Mendeleev wasable to predict the properties of elements that were yet to be discovered

In most cases Mendeleevrsquos predictions (and the blanks in the table)closely matched the characteristics of new elements as they were discoveredFigure 3-18 on pages 72ndash73 shows samples of the elements in their arrange-ment in the periodic table The standard modern version of the periodic tableincludes more than 100 elements Yoursquoll study the periodic table in greaterdetail later in this textbook In fact the periodic table remains a dynamic toolas scientists continue to discover new elements

CompoundsTake a moment to recall what you have learned about the organization of mat-ter using Figure 3-17 as a guide You know that matter is classified as puresubstances and mixtures As you learned in the previous section mixtures canbe homogeneous or heterogeneous You also know that elements are pure sub-stances that cannot be separated into simpler substances There is yet anotherclassification of pure substancesmdashcompounds A compound is a combina-tion of two or more different elements that are combined chemically Mostof the substances that you are familiar with and in fact much of the matterof the universe are compounds Water table salt table sugar and aspirin areexamples of common compounds

Today there are approximately 10 million known compounds and newcompounds continue to be developed and discovered at the rate of about100 000 per year Can you recall some of the medicinal compounds that havemade headlines in recent years There appears to be no limit to the numberof compounds that can be made or that will be discovered Considering thisvirtually limitless potential several organizations have assumed the task ofcollecting data and indexing the known chemical compounds These organi-zations maintain huge databases that allow researchers to access informationon existing compounds The databases and retrieval tools enable scientists tobuild the body of chemical knowledge in an efficient manner

The chemical symbols of the periodic table make it easy to write the for-mulas for chemical compounds For example table salt or sodium chlorideis composed of one part sodium (Na) and one part chlorine (Cl) and its chem-ical formula is NaCl Water is composed of two parts hydrogen (H) to one partoxygen (O) and its formula is H2O

34 Elements and Compounds 71

Figure 3-17

The concept of matter is far-reaching and can be overwhelm-ing But when broken down asshown here it becomes clearhow elements compounds sub-stances and mixtures define allmatter

Chem MC-071

null

16906535

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
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                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
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Page 19: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

72 Chapter 3 MattermdashProperties and Changes

IA1

IIA2

IIIB IVB VB VIB VIIB VIII3 4 5 6 7 8 9

101 H

693 Li

23011 Na 243

12 Mg

39119 K

85537 Rb

132955 Cs

22387 Fr

22789 Ac

138957 La

23290 Th

140158 Ce

23191 Pa

140959 Pr

23892 U

144260 Nd

23793 Np

14561 Pm

904 Be

40120 Ca

87638 Sr

137356 Ba

22688 Ra

45021 Sc

88939 Y

138957 La

22789 Ac

47922 Ti

91240 Zr

178572 Hf

261104 Rf

50923 V

92941 Nb

180973 Ta

262105 Db

52024 Cr

95942 Mo

183874 W

266106 Sg

54925 Mn

9843 Tc

186275 Re

264107 Bh

55826 Fe

101144 Ru

190276 Os

269108 Hs

58927 Co

102945 Rh

192277 Ir

268109 Mt

22 min 1600 a 22 a 65 s 34 s 21 s 440 ms

42middot106a

21middot106a14middot1010a 33middot104a 45middot109a22 a

18 a

93 s 70 ms

11

22

33

44

55

66

77

Periodic Table

Figure 3-18

The periodic table shown aboveillustrates samples of many ofthe elements Be sure to use theperiodic table on pages 156-157for reference throughout yourchemistry course

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 20: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

34 Elements and Compounds 73

VIIIA18

IB IIB10 11 12

IIIA IVA VA VIA VIIA13 14 15 16 17

24494 Pu

150462 Sm

24395 Am

152063 Eu

24796 Cm

157364 Gd

24797 Bk

158965 Tb

25198 Cf

162566 Dy

25299 Es

164967 Ho

257100 Fm

167368 Er

258101 Md

168969 Tm

259102 No

173070 Yb

262103 Lr

175071 Lu

58728 Ni

106446 Pd

195178 Pt

273110

63529 Cu

107947 Ag

197079 Au

272111

65430 Zn

112448 Cd

200680 Hg

69731 Ga

114849 In

204481 Tl

72632 Ge

118750 Sn

207282 Pb

74933 As

121851 Sb

209083 Bi

79034 Se

127652 Te

20984 Po

79935 Br

126953 I

21085 At

83836 Kr

27013 Al 281

14 Si 31015 P 321

16 S 35517 Cl 399

18 Ar

1085 B 120

6 C 1407 N 160

8 O 1909 F 202

10 Ne

402 He

131354 Xe

22286 Rn

277112

102 a 81 h

16middot107a80middot107a 7400 a 1400 a 900 a 472 d 101 d 52 d 58 min 36 h

38 d

118 ms 15 ms 024 ms

of the Elements

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 21: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Unlike elements compounds can be broken down into simpler substancesby chemical means In general compounds that naturally occur are more sta-ble than the individual component elements To separate a compound into itselements often requires external energy such as heat or electricity Figure 3-19shows the apparatus used to produce the chemical change of water into its com-ponent elements of hydrogen and oxygen through a process called electrolysisHere one end of a long platinum electrode is exposed to the water in the tubeand the other end is attached to a power source An electric current splits waterinto hydrogen gas in the compartment on the right and oxygen gas in the com-partment on the left Because water is composed of two parts hydrogen and onepart oxygen there is twice as much hydrogen gas than oxygen gas

The properties of a compound are different from those of its componentelements The example of water in Figure 3-19 illustrates this fact Water isa stable compound that is liquid at room temperature When water is broken

down into its components it is obvious that hydro-gen and oxygen are dramatically different than theliquid they form when combined Oxygen andhydrogen are tasteless odorless gases that vigor-ously undergo chemical reactions with many ele-ments This difference in properties is a result of achemical reaction between the elements Figure 3-20 shows the component elements (sodium andchlorine) of the compound commonly called tablesalt (sodium chloride) When sodium and chlorinereact with each other the compound sodium chlo-ride is formed Note how different the properties ofsodium chloride are from its component elementsSodium is a highly reactive element that fizzes andburns when added to water Chlorine is a poison-ous pale green gas Sodium chloride however isa white unreactive solid that flavors many of thefoods you eat

74 Chapter 3 MattermdashProperties and Changes

Figure 3-19

This classic apparatus called aHoffman apparatus and othersimilar designs are used to sepa-rate water into its components

Figure 3-20

Compounds such as sodium chlo-ride (table salt) are oftenremarkably different from thecomponents that comprise them

Sodium

Chlorine

Sodiumchloride

Chem MC-074

null

11723543

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 22: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Law of Definite ProportionsAn important characteristic of compounds is that the elements comprisingthem combine in definite proportions by mass This observation is so funda-mental that it is summarized as the law of definite proportions This lawstates that regardless of the amount a compound is always composed of thesame elements in the same proportion by mass For example consider thecompound table sugar (sucrose) which is composed of carbon hydrogen andoxygen The analysis of 2000 g of sucrose from a bag of sugar is given inTable 3-4 Note that in Column 1 the sum of the individual masses of the ele-ments equals 2000 g the amount of sucrose that was analyzed This demon-strates the law of conservation of mass as applied to compounds The massof the compound is equal to the sum of the masses of the elements that makeup the compound Column 2 shows the ratio of the mass of each element tothe total mass of the compound as a percentage called the percent by mass

percent by mass () mmas

asss

ofof

coemlem

poeunntd 100

Now letrsquos suppose you analyzed 5000 g of sucrose isolated from a sampleof sugar cane The analysis is shown in Table 3-5 Note in Column 2 thatthe percent by mass values equal those in Column 2 in Table 3-4 Accordingto the law of definite proportions samples of a compound from any sourcemust have the same mass proportions Conversely compounds with differentmass proportions must be different compounds Thus you can conclude thatsamples of sucrose always will be composed of 422 carbon 650 hydro-gen and 5130 oxygen

34 Elements and Compounds 75

Sucrose Analysis from Bag Sugar

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 844 g carbon 100 422 carbon

Hydrogen 130 g hydrogen 100 650 hydrogen

Oxygen 1026 g oxygen 100 5130 oxygen

Total 2000 g sucrose 1000

Table 3-4

Sucrose Analysis from Sugar Cane

Column 1 Column 2

Element Analysis by mass (g) Percent by mass ()

Carbon 2110 g carbon 100 4220 carbon

Hydrogen 325 g hydrogen 100 650 hydrogen

Oxygen 2565 g oxygen 100 5130 oxygen

Total 5000 g sucrose 10000

Table 3-5

200804

g4

sguc

Crose

200103

g0

sguc

Hrose

2010002g6sguc

Orose

5002101g0

sugcCrose

500302

g5

sguc

Hrose

5002506g5

sguc

Orose

HistoryCONNECTION

Antoine-Laurent Lavoisier(1743ndash1794) is recognized as

the father of modern chemistryWhile his fellow scientists tried toexplain matter based on the ele-ments fire earth air and waterLavoisier performed some of thefirst quantitative chemical experi-ments His data and observationsled to the statement of the lawof conservation of mass He alsostudied the nature of combustionand devised a system of namingelements

Lavoisier is credited withdetermining that water resultsfrom the combination of the ele-ments oxygen and hydrogen Healso studied respiration in ani-mals and plants and defined therole of oxygen in the process ofrespiration He determined thathumans take in oxygen and giveoff carbon dioxide during respira-tion

Lavoisier wrote several booksincluding Treatise on ChemicalElements 1789 in which he fur-ther defined the nature of ele-ments and Method of ChemicalNomenclature 1787 describinghis idea for a chemical namingsystem which eventally served asthe basis for the naming systemof modern chemistry

Chem MC-075

null

10861547

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 23: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

76 Chapter 3 MattermdashProperties and Changes

PRACTICE PROBLEMS20 A 780-g sample of an unknown compound contains 124 g of hydro-

gen What is the percent by mass of hydrogen in the compound

21 If 10 g of hydrogen reacts completely with 190 g of fluorine what isthe percent by mass of hydrogen in the compound that is formed

22 If 35 g of X reacts with 105 g of Y to form the compound XY what isthe percent by mass of X in the compound The percent by mass of Y

23 Two unknown compounds are tested Compound I contains 150 g ofhydrogen and 1200 g of oxygen Compound II contains 20 g ofhydrogen and 320 g of oxygen Are the compounds the same

24 All you know about two unknown compounds is that they have thesame percent by mass of carbon With only this information can yoube sure the two compounds are the same

Law of Multiple ProportionsCompounds composed of different elements are obviously different com-pounds Can compounds that are composed of the same elements differ fromeach other The answer is yes because those different compounds have dif-ferent mass compositions The law of multiple proportions states that whendifferent compounds are formed by a combination of the same elements dif-ferent masses of one element combine with the same relative mass of the otherelement in a ratio of small whole numbers Ratios compare the relativeamounts of any items or substances The comparison can be expressed usingnumbers separated by a colon or as a fraction With regard to the law of mul-tiple proportions ratios express the relationship of elements in a compound

The two distinct compounds water (H2O) and hydrogen peroxide (H2O2)illustrate the law of multiple proportions Each compound contains the sameelements (hydrogen and oxygen) Water is composed of two parts hydrogen(the element that is present in the same amount in both compounds) to onepart oxygen (the element that is present in different amounts in both com-pounds) Hydrogen peroxide is composed of two parts hydrogen and two partsoxygen Hydrogen peroxide differs from water in that it has twice as muchoxygen When we compare the mass of oxygen in hydrogen peroxide to themass of oxygen in water we get the ratio 21

In another example copper (Cu) reacts with chlorine (Cl) under differentsets of conditions to form two different compounds Table 3-6 provides ananalysis of their composition Note that the two copper compounds must bedifferent because they have different percents by mass Compound I contains6420 copper compound II contains 4727 copper Compound I contains3580 chlorine compound II contains 5273 chlorine

Figure 3-21

Bar graph compares the rela-tive masses of copper and chlo-rine in Compound I and bargraph compares the relativemasses of copper and chlorine inCompound II A comparisonbetween the relative masses ofcopper in both compoundsshows a 21 ratio

b

a

Analysis Data of Two Copper Compounds

Mass copper (g) Mass chlorine (g) Mass ratioin 1000 g of in 1000 g of

Compound Cu Cl compound compound mmaassss

CCul

I 6420 3580 6420 3580 1793 g Cu1 g Cl

II 4727 5273 4727 5273 08964 g Cu1 g Cl

Table 3-6

Compound I

Mas

s (g

)

Cu

Cl

1000

2000

Compound II

Mas

s (g

)

Cu Cl

1000

2000

Mass RatioComparison

Mas

s (g

)

1000

2000

II

I

a

b

c

For more practice withpercent by mass andlaw of definite proportions go to

Supplemental PracticeProblemsProblems in Appendix A

Practice

c

Chem MC-076

null

120996864

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 24: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Compare the ratio of the mass of copper to the mass of chlorine for eachcompound (see the last column of Table 3-6 and Figure 3-21) Yoursquoll noticethat the mass ratio of copper to chlorine in compound I (1793) is two timesthe mass ratio of copper to chlorine in compound II (08964)

2000

As the law of multiple proportions states the different masses of copper thatcombine with a fixed mass of chlorine in the two different copper com-pounds shown in Figure 3-22 can be expressed as a small whole-numberratio in this case 21

Considering that there is a finite number of elements that exist today andan exponentially greater number of compounds that are composed of theseelements under various conditions it becomes clear how important the lawof multiple proportions is in chemistry

018799634

gg

CCuugg

CCll

mass ratio compound Imass ratio compound II

34 Elements and Compounds 77

Section 34 Assessment

25 How are elements and compounds similar Howare they different

26 What is the basic organizing feature of the peri-odic table of elements

27 Explain how the law of definite proportionsapplies to compounds

28 What type of compounds are compared in the lawof multiple proportions

29 Thinking Critically Name two elements thathave properties similar to those of element potas-sium (K) To those of krypton (Kr)

30 Interpreting Data Complete the following tableand then analyze the data to determine if com-pounds I and II are the same compound If thecompounds are different use the law of multipleproportions to show the relationship between them

Analysis Data of Two Iron Compounds

Compound Total mass (g) Mass Fe (g) Mass O (g) Mass Fe Mass O

I 7500 5246 2254

II 5600 4353 1247

Figure 3-22

Analyses of the mass ratios ofthe two copper chloride com-pounds shown here indicatethat they are indeed differentcompounds The calculated massratio of compound I to com-pound II is 2000 and fits thedefinition of the law of multipleproportions

chemistrymccomself_check_quiz

Chem MC-077

null

55066444

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
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                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
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                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 25: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Be sure to include safety precau-tions procedure notes and a data table in which torecord your observations

3 Define the terms physical property and chemicalproperty Give an example of each

4 Form a hypothesis regarding what you mightobserve ifa a chemical change occursb a physical change occurs

5 Distinguish between a homogeneous mixture and aheterogeneous mixture

Procedure

1 Obtain 8 cm of copper wire Rub the copper wirewith the sandpaper until it is shiny

2 Measure approximately 25 mL AgNO3 (silvernitrate) solution into a 50-mL beaker CAUTIONDo not allow to contact skin or clothing

3 Make and record an observation of the physicalproperties of the copper wire and AgNO3solution

78 Chapter 3 MattermdashProperties and Changes

Safety Precautions

bull Always wear safety goggles gloves and lab apronbull Silver nitrate is toxic and will harm skin and clothingbull Use caution around a flame

ProblemIs there evidence of a chemi-cal reaction between copperand silver nitrate If so whichelements reacted and what isthe name of the compoundthey formed

Objectivesbull Observe the reactants as

they change into productbull Separate a mixture by

filtrationbull Predict the names of the

products

Materialscopper wireAgNO3 solutionsandpaperstirring rod50-mL graduated

cylinder50-mL beakerfunnel

filter paper250-mL Erlenmeyer

flaskring standsmall iron ringplastic petri dishpaper clipBunsen burnertongs

Matter and ChemicalReactionsOne of the most interesting characteristics of matter and one that

drives the study and exploration of chemistry is the fact thatmatter changes By examining a dramatic chemical reaction such asthe reaction of the element copper and the compound silver nitratein a water solution you can readily observe chemical changeDrawing on one of the fundamental laboratory techniques intro-duced in this chapter you can separate the products Then you willuse a flame test to confirm the identity of the products

CHEMLAB 3

Reaction Observations

Time(min)

Observations

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 26: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

CHEMLAB 79

4 Coil the piece of copper wire to a length that willfit into the beaker Make a hook on the end of thecoil to allow the coil to be suspended from thestirring rod

5 Hook the coil onto the middle of the stirring rodPlace the stirring rod across the top of the beakerimmersing some of the coil in the AgNO3 solution

6 Make and record observations of the wire and thesolution every five minutes for 20 minutes

7 Use the ring stand small iron ring funnelErlenmeyer flask and filter paper to set up a fil-tration apparatus Attach the iron ring to the ringstand Adjust the height of the ring so the end ofthe funnel is inside the neck of the Erlenmeyerflask

8 To fold the filter paper examine the diagrambelow Begin by folding the circle in half thenfold in half again Tear off the lower right cornerof the flap that is facing you This will help thefilter paper stick better to the funnel Open thefolded paper into a cone Place the filter papercone in the funnel

9 Remove the coil from the beaker and dispose ofit as directed by your teacher Some of the solidproduct may form a mixture with the liquid in thebeaker Decant the liquid by slowly pouring itdown the stirring rod into the funnel Solidproduct will be caught in the filter paper Collectthe filtratemdashthe liquid that runs through the filterpapermdashin the Erlenmeyer flask

10 Transfer the clear filtrate to a petri dish

11 Adjust a Bunsen burner flame until it is blueHold the paper clip with tongs in the flame untilno additional color is observed CAUTION Thepaper clip will be very hot

12 Using tongs dip the hot paper clip in the filtrateThen hold the paper clip in the flame Record thecolor you observe

Cleanup and Disposal

1 Dispose of materials as directed by your teacher

2 Clean and return all lab equipment to its properplace

3 Wash hands thoroughly

Analyze and Conclude

1 Classifying Which type of mixture is silvernitrate in water Which type of mixture is formedin step 6 Explain

2 Observing and Inferring Describe the changesyou observed in step 6 Is there evidence achemical change occurred Why

3 Predicting Predict the products formed in step6 You may not know the exact chemical namebut you should be able to make an intuitiveprediction

4 Using Resources Use resources such as the CRCHandbook of Chemistry and Physics the MerckIndex or the Internet to determine the colors ofsilver metal and copper nitrate in water Comparethis information with your observations of thereactants and products in step 6

5 Identifying Metals emit characteristic colors inflame tests Copper emits blue-green light Doyour observations in step 12 confirm the presenceof copper in the filtrate collected in step 9

6 Communicating Express in words the chemicalequation that represents the reaction that occurredin step 6

7 Compare your recorded obser-vations with those of several other lab teamsExplain any differences

Real-World Chemistry

1 Analytical chemists determine the chemicalcomposition of matter Two major branches ofanalytical chemistry are qualitative analysismdashdetermining what is in a substancemdashand quanti-tative analysismdashmeasuring how much substanceResearch and report on a career as an analyticalchemist in the food industry

Error Analysis

CHAPTER 3 CHEMLAB

Tear corner

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 27: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Until the Industrial Revolution the amount of car-bon dioxide (CO2) in the atmosphere was fairly con-stant Since the Industrial Revolution however theburning of fossil fuels has contributed to a signifi-cant increase in the amount of carbon dioxide in theatmosphere As the level of carbon dioxide increasesEarth gradually warms up Too much CO2 in theatmosphere can change the conditions on Earth

Another major source of carbon dioxide may bein the foundation of your building or on the side-walks near your school The production of cementthe key ingredient in concrete releases tremendousamounts of carbon dioxide into the atmosphereChemistry may allow engineers to build ldquogreenbuildingsrdquo that are still practical yet have less ofan impact on the environment

Producing CementCement generally begins with a mixture of lime-stone and sand placed in a kiln which heats it toabout 1480degC As the mixture is heated its chem-ical and physical properties change After heatingthe solid that remains is ground into a fine powderThis is cement To make concrete the cement ismixed with fine particles such as sand coarse par-ticles such as crushed stone and water

During the production of cement carbon diox-ide is released in two ways First when the lime-stone is heated it changes into lime and carbondioxide Second the electrical energy used to heatthe kiln is usually supplied by a power plant thatburns fossil fuels such as coal Fossil fuels alsorelease carbon dioxide and other substances

Using FlyashOne way to reduce the amount of carbon dioxidereleased into the atmosphere is to find a replace-ment for cement in concrete One such replacementis a substance known as flyash Flyash is a wasteproduct that accumulates in the smokestacks ofpower plants when ground coal is burned It is afine gray powder that consists of tiny glass beads

Using flyash offers several advantages Flyashordinarily is dumped in landfills Replacing cementwith flyash can reduce CO2 emissions and prevent

tons of waste from piling up in landfills Flyash alsoproduces better concrete Traditional concrete hasweak zones where tiny cracks allow water to flowthrough Flyash contains fine particles that fillspaces and keep moisture out Flyash also protectsthe steel surrounding the concrete makes the con-crete easier to work with and extends the life of theconcrete structure In fact flyash is so reliable theRomans used natural materials similar to flyash tobuild the concrete dome of the Pantheon

Solutions to environmental problems require awilling commitment from scientists architectsbuilders and owners to look for ways to builddurable structures and protect the environment

1 Communicating Ideas Write a pamphlet forpeople who are building new homes tellingthem about the importance of green buildings

2 Using Resources Investigate issues thatinfluence the decision to use flyash Discussthe advantages and disadvantages of flyash

Investigating the Issue

Green Buildings

CHEMISTRY and

Society

80 Chapter 3 MattermdashProperties and Changes

Visit the Chemistry Web site atchemistrymccom to find links to moreinformation about flyash and green buildings

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 28: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Study Guide 81

CHAPTER STUDY GUIDE3

Vocabulary

Key Equations and Relationships

Summary31 Properties of Matter

bull A substance is a form of matter with a uniform andunchanging composition

bull Physical properties can be observed without alteringa substancersquos composition Chemical propertiesdescribe a substancersquos ability to combine with orchange into one or more new substances

bull Both physical and chemical properties are affected byexternal conditions such as temperature and pressure

bull The three common states of matter are solid liquidand gas

32 Changes in Matterbull A physical change alters the physical properties of a

substance without changing its composition

bull A chemical change also known as a chemical reac-tion involves a change in a substancersquos composition

bull In a chemical reaction reactants form products

bull The law of conservation of mass states that mass isneither created nor destroyed during a chemicalreaction it is conserved

33 Mixtures of Matter

bull A mixture is a physical blend of two or more puresubstances in any proportion

bull Solutions are homogeneous mixtures

bull Mixtures can be separated by physical meansCommon separation techniques include filtrationdistillation crystallization and chromatography

34 Elements and Compoundsbull Elements are substances that cannot be broken down

into simpler substances by chemical or physicalmeans

bull The elements are organized in the periodic table ofelements

bull A compound is a chemical combination of two ormore elements Properties of compounds differ fromthe properties of their component elements

bull The law of definite proportions states that a com-pound is always composed of the same elements inthe same proportions

bull The law of multiple proportions states that if ele-ments form more than one compound those com-pounds will have compositions that are smallwhole-number multiples of each other

bull law of conservation of mass (p 63)Massreactants Massproducts

bull percent by mass MMaasss

c

s

o

e

m

le

p

m

o

e

u

n

n

t

d 100

(p 75)

bull chemical change (p 62)bull chemical property (p 57)bull chromatography (p 69)bull compound (p 71)bull crystallization (p 69)bull distillation (p 69)bull element (p 70)bull extensive properties (p 56)bull filtration (p 68 )bull gas (p 59)

bull heterogeneous mixture (p 67)bull homogeneous mixture (p 67)bull intensive properties (p 56)bull law of conservation of mass

(p 63)bull law of definite proportions

(p 75)bull law of multiple proportions

(p 76)bull liquid (p 58)

bull mixture (p 66)bull percent by mass (p 75)bull periodic table (p 70)bull physical changes (p 61)bull physical property (p 56)bull solid (p 58)bull solution (p 67)bull states of matter (p 58)bull substance (p 55)bull vapor (p 59)

chemistrymccomvocabulary_puzzlemaker

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 29: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

82 Chapter 3 MattermdashProperties and Changes

Go to the Chemistry Web site atchemistrymccom for additionalChapter 3 Assessment

Concept Mapping31 Organize the following terms into a logical concept

map state physical properties virtually incompress-ible solid gas liquid tightly packed particles com-pressible incompressible particles far apart looselypacked particles

Mastering Concepts32 List three examples of substances Explain why each

is a substance (31)

33 List at least three physical properties of tap water (31)

34 Identify each of the following as an extensive or inten-sive physical property (31)

a melting pointb massc densityd length

35 ldquoProperties are not affected by changes in temperatureand pressurerdquo Is this statement true or false Explain(31)

36 Classify each of the following as either solid liquidor gas at room temperature (31)

a milkb airc copperd heliume diamondf candle wax

37 Classify each of the following as a physical propertyor a chemical property (31)

a aluminum has a silvery colorb gold has a density of 19 gcm3

c sodium ignites when dropped in waterd water boils at 100degCe silver tarnishesf mercury is a liquid at room temperature

38 A carton of milk is pouredinto a bowl Describe thechanges that occur in themilkrsquos shape and volume(31)

39 Classify each of the follow-ing as a physical change or a chemical change (32)

a breaking a pencil in twob water freezing and forming icec frying an eggd burning woode leaves turning color in the fall

40 Is a change in phase a physical change or a chemicalchange Explain (32)

41 List four indicators that a chemical change has proba-bly taken place (32)

42 Iron and oxygen combine to form iron oxide (rust)List the reactants and products of this reaction (32)

43 Use Table 3-1 to identify a substance that undergoes aphase change as its temperature increases from 250degCto 210degC What phase change takes place (32)

44 After burning for three hours acandle has lost half of its massExplain why this example doesnot violate the law of conservationof mass (32)

45 Describe the difference between aphysical change and a chemicalchange (32)

46 Describe the characteristics of amixture (33)

47 Describe a method that could be used to separate eachof the following mixtures (33)

a iron filings and sandb sand and saltc the components of inkd helium and oxygen gases

48 ldquoA mixture is the chemical bonding of two or moresubstances in any proportionrdquo Is this statement true orfalse Explain

CHAPTER ASSESSMENTCHAPTER ASSESSMENT3

1

2

4 53

7 86

10 119

chemistrymccomchapter_test

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 30: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Assessment 83

CHAPTER 3 ASSESSMENT

49 Which of the following are the same and which aredifferent (33)

a a substance and a pure substanceb a heterogeneous mixture and a solutionc a substance and a mixtured a homogeneous mixture and a solution

50 Describe how a homogeneous mixture differs from aheterogeneous mixture (33)

51 A chemistry professor has developed a laboratory taskto give her students practical experience using basicseparation techniques She prepares a liquid solutionof water and another compound Assuming you are astudent in the class name the technique you would useto separate and identify the components Give specificdetails of the method

52 State the definition of an element (34)

53 Name the elements contained in the following compounds (34)

a sodium chloride (NaCl) c ethanol (C2H6O)b ammonia (NH3) d bromine (Br2)

54 How many naturally occurring elements are found onEarth Approximately how many synthetic elementshave been identified (34)

55 What was Dmitri Mendeleevrsquos major contribution tothe field of chemistry (34)

56 Is it possible to distinguish between an element and acompound Explain (34)

57 How are the properties of a compound related to thoseof the elements that comprise it (34)

58 How are the elements contained within a group on theperiodic table related (34)

59 Which law states that a compound always contains thesame elements in the same proportion by mass (34)

Mastering ProblemsProperties of Matter (31)60 A scientist is given the task of identifying an unknown

compound on the basis of its physical properties Thesubstance is a white solid at room temperatureAttempts to determine its boiling point were unsuc-cessful Using Table 3-1 name the unknown com-pound

Conservation of Mass (32)61 A 280-g sample of nitrogen gas combines completely

with 60 g of hydrogen gas to form ammonia What isthe mass of ammonia formed

62 A substance breaks down into its component elementswhen it is heated If 680 grams of the substance ispresent before it is heated what is the combined massof the component elements after heating

63 A 130-g sample of X combines with a 340-g sampleof Y to form the compound XY2 What is the mass ofthe reactants

64 Sodium chloride can be formed by the reaction ofsodium metal and chlorine gas If 4598 g of sodiumcombines with an excess of chlorine gas to form11689 g sodium chloride what mass of chlorine gasis used in the reaction

65 Copper sulfide is formed when copper and sulfur areheated together In this reaction 127 g of copper reactswith 41 g of sulfur After the reaction is complete 9 gof sulfur remains unreacted What is the mass of cop-per sulfide formed

Law of Definite Proportions (34)66 A 253-g sample of an unknown compound contains

08 g of oxygen What is the percent by mass of oxy-gen in the compound

67 Magnesium combines with oxygen to form magne-sium oxide If 1057 g of magnesium reacts com-pletely with 696 g of oxygen what is the percent bymass of oxygen in magnesium oxide

68 When mercury oxide is heated it decomposes intomercury and oxygen If 284 g of mercury oxidedecomposes producing 20 g oxygen what is the per-cent by mass of mercury in mercury oxide

Law of Multiple Proportions (34)69 Carbon reacts with oxygen to form two different com-

pounds Compound I contains 482 g carbon for every644 g of oxygen Compound II contains 2013 g carbonfor every 537 g of oxygen What is the ratio of carbonto a fixed mass of oxygen for the two compounds

Mixed ReviewSharpen your problem-solving skills by answering the following

70 Which state of matter is the most compressible Theleast Explain why

Solid Liquid Gas

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 31: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Energy Released by Carbon

Mass (g) Energy released (kJ)

100 33

200 66

300 99

400 132

84 Chapter 3 MattermdashProperties and Changes

71 Classify each of the following as a homogeneous mix-ture or a heterogeneous mixture (33)

a brass (an alloy of zinc and copper)b a saladc bloodd powder drink mix dissolved in water

72 Phosphorus combines with hydrogen to form phos-phine In this reaction 1239 g of phosphorus com-bines with excess hydrogen to produce 1299 g ofphosphine After the reaction 310 g of hydrogenremains unreacted What mass of hydrogen is used inthe reaction What was the initial mass of hydrogenbefore the reaction

73 A sample of a certain lead compound contains 646grams of lead for each gram of oxygen A second sam-ple has a mass of 6854 g and contains 2876 g of oxy-gen Are the two samples the same

Thinking Critically74 Applying Concepts Air is a mixture of many

gases primarily nitrogen oxygen and argon Coulddistillation be used to separate air into its componentgases Explain

75 Interpreting Data A compound contains elementsX and Y Four samples with different masses wereanalyzed and the masses of X and Y in each samplewere plotted on a graph The samples are labeled I IIIII and IV

a Which samples are from the same compound Howdo you know

b What is the approximate ratio of mass X to mass Yin the samples that are from the same compound

c What is the approximate ratio of mass X to mass Yin the sample(s) that are not from the samecompound

Writing in Chemistry76 Select a synthetic element and prepare a short written

report on its development Be sure to cover recent dis-coveries list major research centers that conduct thistype of research and describe the properties of thesynthesized element

77 Research the life of a scientist other than Mendeleevwho contributed to the development of the modernperiodic table of elements Write a brief biographyof this person and detail his or her scientificaccomplishments

78 The results and interpretations of chemistry experi-ments and studies are recorded and published in liter-ally hundreds of scientific journals around the worldVisit the local library and look at several of the articlesin a chemistry journal such as The Journal of theAmerican Chemical Society Write a brief summary ofyour observations regarding the format and style ofwriting in chemistry

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

79 What is chemistry (Chapter 1)

80 What is mass Weight (Chapter 1)

81 Express the following in scientific notation(Chapter 2)

a 34 500 d 789b 2665 e 75 600c 09640 f 0002 189

82 Perform the following operations (Chapter 2)

a 107 103

b (14 103) (51 105)c (2 103) (4 105)

83 Convert 65degC to Kelvins (Chapter 2)

84 Graph the following data What is the slope of theline (Chapter 2)

CHAPTER ASSESSMENT3

0 2 4 6 8

Mas

s o

f X

(g

)

40

30

20

10

Mass of Y (g)

II

III

I

IV

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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Page 32: Chapter 3: Matter-Properties and Changes€¢ Good conductor of heat and electricity • Density 8.92 g/cm3 •Melting point 1085°C • Boiling point 2570°C •Forms green copper

Standardized Test Practice 85

Use these questions and the test-taking tip to preparefor your standardized test

Interpreting Tables Use the table to answerquestions 1 and 2

1 What are the values for Cl and F respectively forSample II

a 0622 and 6165b 6165 and 3835c 3835 and 0622d 3835 and 6165

2 Which of the following statements best describes therelationship between the two samples

a The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of definite proportions

b The compound in Sample I is the same as in SampleII Therefore the mass ratio of Cl to F in bothsamples will obey the law of multiple proportions

c The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to F inboth samples will obey the law of proportions

d The compound in Sample I is not the same as inSample II Therefore the mass ratio of Cl to Fin both samples will obey the law of multipleproportions

3 After elements A and B react to completion in a closedcontainer the ratio of masses of A and B in the con-tainer will be the same as before the reaction This istrue because of the law of

a definite proportionsb multiple proportionsc conservation of massd conservation of energy

4 All of the following are physical properties of tablesugar (sucrose) EXCEPT

a forms solid crystals at room temperatureb appears as crystals white in colorc breaks down into carbon and water vapor when

heatedd tastes sweet

5 A substance is said to be in the solid state if

a it is hard and rigidb it can be compressed into a smaller volumec it takes the shape of its containerd its matter particles are close together

6 Na K Li and Cs all share very similar chemicalproperties In the periodic table of elements they mostlikely belong to the same

a row c groupb period d element

7 A heterogeneous mixture

a cannot be separated by physical meansb is composed of distinct areas of compositionc is also called a solutiond has the same composition throughout

8 What is the percent by mass of sulfur in sulfuric acidH2SO4

a 3269 c 1631b 6413 d 4857

9 Magnesium reacts explosively with oxygen to formmagnesium oxide All of the following are true of thisreaction EXCEPT

a The mass of magnesium oxide produced equals themass of magnesium consumed plus the mass ofoxygen consumed

b The reaction describes the formation of a newsubstance

c The product of the reaction magnesium oxide is achemical compound

d Magnesium oxide has physical and chemicalproperties similar to both oxygen and magnesium

10 Which of the following is NOT a chemical reaction

a dissolution of sodium chloride in waterb combustion of gasolinec fading of wallpaper by sunlightd curdling of milk

STANDARDIZED TEST PRACTICECHAPTER 3

When Eliminating Cross It Out Considereach answer choice individually and cross outchoices yoursquove eliminated If you canrsquot write in thetest booklet use the scratch paper List the answerchoice letters on the scratch paper and cross themout there Yoursquoll save time and stop yourself fromchoosing an answer yoursquove mentally eliminated

Mass Analysis of Two ChlorinendashFluorineCompound Samples

Sample Mass chlorine Mass fluorine Cl F(g) (g)

I 13022 6978 6511 3489

II 5753 9248

chemistrymccomstandardized_test

  • Chemistry Matter and Change
    • Contents in Brief
      • Table of Contents
        • Chapter 1 Introduction to Chemistry
          • Discovery Lab Where is it
          • Section 11 The Stories of Two Chemicals
            • Chemistry Online
              • Section 12 Chemistry and Matter
                • Problem-Solving Lab Chemical Models
                • Careers Using Chemistry Chemistry Teacher
                  • Section 13 Scientific Methods
                  • Section 14 Scientific Research
                    • Biology Connection
                    • ChemLab The Rubber Band Stretch
                    • MiniLab Developing Observation Skills
                      • Chemistry and Society The Human Genome Project
                      • Chapter 1 Study Guide
                      • Chapter 1 Assessment
                        • Chapter 2 Data Analysis
                          • Discovery Lab Layers of Liquids
                          • Section 21 Units of Measurement
                            • Astronomy Connection
                            • Chemistry Online
                            • MiniLab Density of an Irregular Solid
                              • Section 22 Scientific Notation and Dimensional Analysis
                              • Section 23 How reliable are measurements
                                • Careers Using Chemistry Scientific Illustrator
                                  • Section 24 Representing Data
                                    • Problem-Solving Lab How does speed affect stopping distance
                                    • ChemLab Using Density to Find the Thickness of a Wire
                                      • How It Works Ultrasound Devices
                                      • Chapter 2 Study Guide
                                      • Chapter 2 Assessment
                                        • Chapter 3 Matter-Properties and Changes
                                          • Discovery Lab Observing Chemical Change
                                          • Section 31 Properties of Matter
                                            • Careers Using Chemistry Science Writer
                                            • Problem-Solving Lab How is compressed gas released
                                              • Section 32 Changes in Matter
                                                • ChemLab Matter and Chemical Reactions
                                                  • Section 33 Mixtures of Matter
                                                    • MiniLab Separating Ink Dyes
                                                    • Chemistry Online
                                                      • Section 34 Elements and Compounds
                                                        • History Connection
                                                          • Chemistry and Society Green Buildings
                                                          • Chapter 3 Study Guide
                                                          • Chapter 3 Assessment
                                                            • Chapter 4 The Structure of the Atom
                                                              • Discovery Lab Observing Electrical Charge
                                                              • Section 41 Early Theories of Matter
                                                                • History Connection
                                                                • ChemLab Very Small Particles
                                                                  • Section 42 Subatomic Particles and the Nuclear Atom
                                                                    • Chemistry Online
                                                                    • Problem-Solving Lab Interpreting STM Images
                                                                      • Section 43 How Atoms Differ
                                                                        • MiniLab Modeling Isotopes
                                                                          • Section 44 Unstable Nuclei and Radioactive Decay
                                                                            • Careers Using Chemistry Radiation Protection Technician
                                                                              • Chemistry and Society Nanotechnology
                                                                              • Chapter 4 Study Guide
                                                                              • Chapter 4 Assessment
                                                                                • Chapter 5 Electrons in Atoms
                                                                                  • Discovery Lab Whats Inside
                                                                                  • Section 51 Light and Quantized Energy
                                                                                    • Chemistry Online
                                                                                    • MiniLab Flame Tests
                                                                                    • ChemLab Line Spectra
                                                                                      • Section 52 Quantum Theory and the Atom
                                                                                        • Problem-Solving Lab How was Bohrs atomic model able to explain the line spectrum of hydrogen
                                                                                        • Physics Connection
                                                                                          • Section 53 Electron Configurations
                                                                                            • Careers Using Chemistry Spectroscopist
                                                                                              • How It Works Lasers
                                                                                              • Chapter 5 Study Guide
                                                                                              • Chapter 5 Assessment
                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                  • Discovery Lab Versatile Metals
                                                                                                  • Section 61 Development of the Modern Periodic Table
                                                                                                    • Astronomy Connection
                                                                                                    • Problem-Solving Lab Francium-solid liquid or gas
                                                                                                    • ChemLab Descriptive Chemistry of the Elements
                                                                                                      • Section 62 Classification of the Elements
                                                                                                        • Chemistry Online
                                                                                                        • Careers Using Chemistry Medical Lab Technician
                                                                                                          • Section 63 Periodic Trends
                                                                                                            • MiniLab Periodicity of Molar Heats of Fusion and Vaporization
                                                                                                              • How It Works Television Screen
                                                                                                              • Chapter 6 Study Guide
                                                                                                              • Chapter 6 Assessment
                                                                                                                • Chapter 7 The Elements
                                                                                                                  • Discovery Lab Magnetic Materials
                                                                                                                  • Section 71 Properties of s-Block Elements
                                                                                                                    • Careers Using Chemistry Dietician
                                                                                                                    • MiniLab Properties of Magnesium
                                                                                                                    • ChemLab Hard Water
                                                                                                                      • Section 72 Properties of p-Block Elements
                                                                                                                        • History Connection
                                                                                                                        • Problem-Solving Lab Cost of Fertilizer
                                                                                                                          • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                            • Chemistry Online
                                                                                                                              • How It Works Semiconductor Chips
                                                                                                                              • Chapter 7 Study Guide
                                                                                                                              • Chapter 7 Assessment
                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                  • Discovery Lab An Unusual Alloy
                                                                                                                                  • Section 81 Forming Chemical Bonds
                                                                                                                                  • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                    • Chemistry Online
                                                                                                                                    • ChemLab Making Ionic Compounds
                                                                                                                                    • Problem-Solving Lab How is color related to a transferred electron
                                                                                                                                      • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                        • Careers Using Chemistry Wastewater Treatment Operator
                                                                                                                                        • Earth Science Connection
                                                                                                                                          • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                            • MiniLab Heat Treatment of Steel
                                                                                                                                              • Everyday Chemistry Color of Gems
                                                                                                                                              • Chapter 8 Study Guide
                                                                                                                                              • Chapter 8 Assessment
                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                  • Discovery Lab Oil and Vinegar Dressing
                                                                                                                                                  • Section 91 The Covalent Bond
                                                                                                                                                  • Section 92 Naming Molecules
                                                                                                                                                    • Careers Using Chemistry Organic Chemist
                                                                                                                                                      • Section 93 Molecular Structures
                                                                                                                                                      • Section 94 Molecular Shape
                                                                                                                                                        • MiniLab Building VSEPR Models
                                                                                                                                                          • Section 95 Electronegativity and Polarity
                                                                                                                                                            • History Connection
                                                                                                                                                            • ChemLab Chromatography
                                                                                                                                                            • Chemistry Online
                                                                                                                                                            • Problem-Solving Lab How do dispersion forces determine the boiling point of a substance
                                                                                                                                                              • How It Works Microwave Oven
                                                                                                                                                              • Chapter 9 Study Guide
                                                                                                                                                              • Chapter 9 Assessment
                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                  • Discovery Lab Observing a Change
                                                                                                                                                                  • Section 101 Reactions and Equations
                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                      • Section 102 Classifying Chemical Reactions
                                                                                                                                                                        • Problem-Solving Lab Can you predict the reactivities of halogens
                                                                                                                                                                        • ChemLab Small Scale Activities of Metals
                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                          • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                            • MiniLab Observing a Precipitate-Forming Reaction
                                                                                                                                                                            • Careers Using Chemistry Pastry Chef
                                                                                                                                                                              • How It Works Hot and Cold Packs
                                                                                                                                                                              • Chapter 10 Study Guide
                                                                                                                                                                              • Chapter 10 Assessment
                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                  • Discovery Lab How much is a mole
                                                                                                                                                                                  • Section 111 Measuring Matter
                                                                                                                                                                                    • History Connection
                                                                                                                                                                                      • Section 112 Mass and the Mole
                                                                                                                                                                                        • Problem-Solving Lab Molar Mass Avogadros Number and the Atomic Nucleus
                                                                                                                                                                                          • Section 113 Moles of Compounds
                                                                                                                                                                                          • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                            • Careers Using Chemistry Analytical Chemist
                                                                                                                                                                                            • MiniLab Percent Composition and Gum
                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                              • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                • ChemLab Hydrated Crystals
                                                                                                                                                                                                  • Chemistry and Technology Making Medicines
                                                                                                                                                                                                  • Chapter 11 Study Guide
                                                                                                                                                                                                  • Chapter 11 Assessment
                                                                                                                                                                                                    • Chapter 12 Stoichiometry
                                                                                                                                                                                                      • Discovery Lab Observing a Chemical Reaction
                                                                                                                                                                                                      • Section 121 What is stoichiometry
                                                                                                                                                                                                        • Careers Using Chemistry Pharmacist
                                                                                                                                                                                                          • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                            • ChemLab A Mole Ratio
                                                                                                                                                                                                            • MiniLab Baking Soda Stoichiometry
                                                                                                                                                                                                              • Section 123 Limiting Reactants
                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                • Biology Connection
                                                                                                                                                                                                                  • Section 124 Percent Yield
                                                                                                                                                                                                                    • Problem-Solving Lab How does the surface area of a solid reactant affect percent yield
                                                                                                                                                                                                                      • How It Works Air Bags
                                                                                                                                                                                                                      • Chapter 12 Study Guide
                                                                                                                                                                                                                      • Chapter 12 Assessment
                                                                                                                                                                                                                        • Chapter 13 States of Matter
                                                                                                                                                                                                                          • Discovery Lab Defying Density
                                                                                                                                                                                                                          • Section 131 Gases
                                                                                                                                                                                                                            • Problem-Solving Lab How are the depth of a dive and pressure related
                                                                                                                                                                                                                              • Section 132 Forces of Attraction
                                                                                                                                                                                                                              • Section 133 Liquids and Solids
                                                                                                                                                                                                                                • MiniLab Crystal Unit Cell Models
                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                • Careers Using Chemistry Materials Engineer
                                                                                                                                                                                                                                  • Section 134 Phase Changes
                                                                                                                                                                                                                                    • ChemLab Small Scale Comparing Rates of Evaporation
                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                      • Everyday Chemistry Metals with a Memory
                                                                                                                                                                                                                                      • Chapter 13 Study Guide
                                                                                                                                                                                                                                      • Chapter 13 Assessment
                                                                                                                                                                                                                                        • Chapter 14 Gases
                                                                                                                                                                                                                                          • Discovery Lab More Than Just Hot Air
                                                                                                                                                                                                                                          • Section 141 The Gas Laws
                                                                                                                                                                                                                                            • Careers Using Chemistry Meteorologist
                                                                                                                                                                                                                                            • History Connection
                                                                                                                                                                                                                                            • Problem-Solving Lab How is turbocharging in a car engine maximized
                                                                                                                                                                                                                                              • Section 142 The Combined Gas Law and Avogadros Principle
                                                                                                                                                                                                                                              • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                • ChemLab Using the Ideal Gas Law
                                                                                                                                                                                                                                                • MiniLab The Density of Carbon Dioxide
                                                                                                                                                                                                                                                  • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                      • Chemistry and Technology Giving a Lift to Cargo
                                                                                                                                                                                                                                                      • Chapter 14 Study Guide
                                                                                                                                                                                                                                                      • Chapter 14 Assessment
                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                          • Discovery Lab Solution Formation
                                                                                                                                                                                                                                                          • Section 151 What are solutions
                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                              • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                • ChemLab CBL Beers Law
                                                                                                                                                                                                                                                                  • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                    • MiniLab Freezing Point Depression
                                                                                                                                                                                                                                                                    • Careers Using Chemistry Renal Dialysis Technician
                                                                                                                                                                                                                                                                      • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                        • Problem-Solving Lab How can you measure the turbidity of a colloid
                                                                                                                                                                                                                                                                          • Chemistry and Society Sickle-Cell Disease
                                                                                                                                                                                                                                                                          • Chapter 15 Study Guide
                                                                                                                                                                                                                                                                          • Chapter 15 Assessment
                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                              • Discovery Lab Temperature of a Reaction
                                                                                                                                                                                                                                                                              • Section 161 Energy
                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                  • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                    • ChemLab Calorimetry
                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Heating and Cooling Specialist
                                                                                                                                                                                                                                                                                      • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How much energy is needed to heat water from a solid to a vapor
                                                                                                                                                                                                                                                                                        • MiniLab Enthalpy of Fusion for Ice
                                                                                                                                                                                                                                                                                          • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                          • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                            • Earth Science Connection
                                                                                                                                                                                                                                                                                              • How It Works Refrigerator
                                                                                                                                                                                                                                                                                              • Chapter 16 Study Guide
                                                                                                                                                                                                                                                                                              • Chapter 16 Assessment
                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                  • Discovery Lab Speeding Reactions
                                                                                                                                                                                                                                                                                                  • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                    • Problem-Solving Lab Speed and Energy of Collision
                                                                                                                                                                                                                                                                                                      • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                        • ChemLab Concentration and Reaction Rate
                                                                                                                                                                                                                                                                                                        • MiniLab Examining Reaction Rate and Temperature
                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                          • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                            • Physics Connection
                                                                                                                                                                                                                                                                                                              • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry Food Technologist
                                                                                                                                                                                                                                                                                                                  • How It Works Catalytic Converter
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Study Guide
                                                                                                                                                                                                                                                                                                                  • Chapter 17 Assessment
                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                      • Discovery Lab Whats equal about equilibrium
                                                                                                                                                                                                                                                                                                                      • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                        • Physics Connection
                                                                                                                                                                                                                                                                                                                          • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Nurse Anesthetist
                                                                                                                                                                                                                                                                                                                            • MiniLab Shifts in Equilibrium
                                                                                                                                                                                                                                                                                                                              • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                • ChemLab Small Scale Comparing Two Solubility Product Constants
                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does fluoride prevent tooth decay
                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology The Haber Process
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Study Guide
                                                                                                                                                                                                                                                                                                                                  • Chapter 18 Assessment
                                                                                                                                                                                                                                                                                                                                    • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Investigating Whats in Your Cupboards
                                                                                                                                                                                                                                                                                                                                      • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Agricultural Technician
                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                        • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                          • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                            • MiniLab Acid Strength
                                                                                                                                                                                                                                                                                                                                              • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                              • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                • ChemLab Standardizing a Base Solution by Titration
                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab How does your blood maintain its pH
                                                                                                                                                                                                                                                                                                                                                  • How It Works Antacids
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Study Guide
                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Assessment
                                                                                                                                                                                                                                                                                                                                                    • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Observing an Oxidation-Reduction Reaction
                                                                                                                                                                                                                                                                                                                                                      • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                        • MiniLab Cleaning by Redox
                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Photochemical Etching Artist
                                                                                                                                                                                                                                                                                                                                                          • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                            • ChemLab Redox Reactions
                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does redox lift a space shuttle
                                                                                                                                                                                                                                                                                                                                                              • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                  • How It Works Photographic Film
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Study Guide
                                                                                                                                                                                                                                                                                                                                                                  • Chapter 20 Assessment
                                                                                                                                                                                                                                                                                                                                                                    • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab A Lemon Battery
                                                                                                                                                                                                                                                                                                                                                                      • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                        • ChemLab CBL Voltaic Cell Potentials
                                                                                                                                                                                                                                                                                                                                                                          • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Electrochemist
                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Interpreting Scientific Illustrations
                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Corrosion
                                                                                                                                                                                                                                                                                                                                                                              • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • History Connection
                                                                                                                                                                                                                                                                                                                                                                                  • Chemistry and Technology Fuel Cells
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Assessment
                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                      • Discovery Lab Viscosity of Motor Oil
                                                                                                                                                                                                                                                                                                                                                                                      • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab Analyzing Hydrocarbon Burner Gases
                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                        • Careers Using Chemistry Alternative Fuel Technician
                                                                                                                                                                                                                                                                                                                                                                                          • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                          • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                            • MiniLab Synthesis and Reactivity of Ethyne
                                                                                                                                                                                                                                                                                                                                                                                              • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab Identifying Structural Geometric and Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                      • Everyday Chemistry Unlimited Alternative Energy
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                          • Discovery Lab Making Slime
                                                                                                                                                                                                                                                                                                                                                                                                          • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                            • Astronomy Connection
                                                                                                                                                                                                                                                                                                                                                                                                              • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab Properties of Alcohols
                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Making an Ester
                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab Categorizing Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Dental Assistant
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Technology Carbon Stronger Than Steel
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 23 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Testing for Simple Sugars
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                    • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab A Saponification Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                        • Problem-Solving Lab How does DNA replicate
                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Personal Trainer
                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Alcoholic Fermentation in Yeast
                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Everyday Chemistry Sense of Smell
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Chain Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Physics Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                        • MiniLab Modeling Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Careers Using Chemistry Radiation Therapist
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab How does distance affect radiation exposure
                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Measuring Naturally Occurring Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chemistry and Society The Realities of Radon
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Discovery Lab Clarification of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Section 261 Earths Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Careers Using Chemistry Environmental Health Inspector
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Earth Science Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • MiniLab Acid Rain in a Bag
                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Section 262 Earths Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Biology Connection
                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chemistry Online
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 263 Earths Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • ChemLab CBL Solar Pond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Problem-Solving Lab Global warming fact or fiction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How It Works Water Softener
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Study Guide
                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Assessment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Appendices
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix A Supplemental Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Appendix B Math Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Arithmetic Operations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations with Scientific Notation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Square and Cube Roots
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Significant Figures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Solving Algebraic Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Unit Conversion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Drawing Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Using Line Graphs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Ratios Fractions and Percents
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Operations Involving Fractions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Logarithms and Antilogarithms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Appendix C Tables
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-1 Color Key
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-2 Symbols and Abbreviations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-3 SI Prefixes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-4 The Greek Alphabet
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-5 Physical Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-6 Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-7 Electron Configurations of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-8 Names and Charges of Polyatomic Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-9 Ionization Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-10 Solubility Guidelines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-11 Specific Heat Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-12 Molal Freezing Point Depression and Boiling Point Elevation Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • C-13 Heat of Formation Values
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix D Solutions to Practice Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Appendix E Try At Home Labs
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • GlossaryGlosario
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Index
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Photo Credits
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Features
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • ChemLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • MiniLab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Problem-Solving Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Discovery Lab
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • How It Works
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Everyday Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Society
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chemistry and Technology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Careers Using Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Connections
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Earth Science
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Biology
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • History
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Astronomy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Physics
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Student Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Study Guide for Content Mastery
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Study Skills
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • How to Use This Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Writing a Laboratory Report
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 11 Laboratory Techniques and Lab Safety
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 12 Effective Use of a Bunsen Burner
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 21 Density
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 22 Making a Graph
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 31 The Density of Wood
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 32 Properties of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 41 Simulation of Rutherfordrsquos Gold Foil Experiment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 42 Half-life of Barium-137m
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 51 The Photoelectric Effect
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 52 Electron Charge to Mass Ratio
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 61 Properties of the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 62 Periodic Trends in the Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 71 Is there potassium in coffee
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 72 The Periodic Puzzle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 81 Properties of Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 82 Formation of a Salt
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 91 Covalent Bonding in Medicines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 92 Covalent Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 101 Single-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 102 Double-Replacement Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 111 Estimating the Size of a Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 112 Mole Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 121 Observing a Limiting Reactant
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 122 Determining Reaction Ratios
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 131 Freezing Bacteria
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 132 Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 141 Charlesrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 142 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 151 Making a Solubility Curve
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 152 Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 161 Heats of Solution and Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 162 Heat of Combustion of Candle Wax
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 171 The Rate of a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 172 Surface Area and Reaction Rate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 181 Reversible Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 182 Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 191 Acids Bases and Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 192 Determining the Percent of Acetic Acid in Vinegar
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 201 Electron-Losing Tendencies of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 202 Determining Oxidation Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 211 Electrolysis of Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 212 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 221 Isomerism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 222 The Ripening of Fruit with Ethene
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 231 The Characterization of Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • 232 Polymerization Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 241 Denaturation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • 242 Saturated and Unsaturated Fats
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 251 Radioisotope Dating
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • 252 Modeling Isotopes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 261 Organisms That Break Down Oil
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • 262 Growth of Algae as a Function of Nitrogen Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Forensics Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Introduction to Forensic Science To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Observing the Scene and Collecting Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Fingerprints
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Forensic Skills Blood Identification
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • The Truth Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Crime A The Counterfeit Coin Caper
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A1 What metal can it be
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A2 Separation of a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab A3 Analyzing and Identifying White Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Crime B The Case of the Problem Patent
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B1 Using Paper Chromatography to Separate a Mixture
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B3 pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Lab B4 Effects of Acids and Bases on the Color of a Dye
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Crime C The Case of the Fallen Walkway
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C1 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C2 Sources and Causes of Corrosion
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab C3 Identifying Sacrificial Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Small-Scale Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 1 Small-Scale Laboratory Techniques
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 2 Comparing the Density of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 3 Separation of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 4 Periodicity and the Properties of Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 5 Properties of Transition Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 6 Modeling Molecular Shapes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 7 Solutions and Precipitates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 8 Determining Avogadrorsquos Number
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 9 Measuring Boiling Point
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 10 Relating Gas Pressure and Gas Volume
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 11 Effect of Temperature on Solubility
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 12 Specific Heat of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 13 Energy Changes in Chemical and Physical Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 14 Determining Reaction Orders
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 15 Observing Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 16 Exploring Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 17 Comparing the Strengths of Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 18 Testing the Acidity of Aspirin
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 19 Reduction of Manganese
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Lab 20 Plants Produce Oxygen
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • CBL Laboratory Manual
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • To the Student
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Organization of Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Sending Data to Graphical Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • CBL Equipment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety in the Laboratory
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Safety Symbols
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Laboratory Activities
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 1 Quantitative and Qualitative Observations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 2 Conductivity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 3 Melting and Freezing Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 4 Boylersquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 5 Gay-Lussacrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 6 Determining Molar Mass Using Freezing Point Depression
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 7 Calorimetry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 8 Hessrsquos Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 9 Determine the Molar Mass of an Unknown Acid
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Lab 10 Reaction Potentials of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • ChemLab and MiniLab Worksheets
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 4
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 6
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 8
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 10
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 12
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 14
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 16
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 18
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 20
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 22
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 24
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 26
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Supplemental Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Solving Problems A Chemistry Handbook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Reviewing Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Student Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter Review Questions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter 26 Chemistry in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chemistry Challenge Problems
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 1 Production of Chlorofluorocarbons 1950ndash1992
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 2 Population Trends in the United States
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 3 Physical and Chemical Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 Isotopes of an Element
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 5 Quantum Numbers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 6 Doumlbereinerrsquos Triads
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 7 Abundance of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Comparing the Structures of Atoms and Ions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 9 Exceptions to the Octet Rule
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 10 Balancing Chemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 11 Using Mole-Based Conversions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Mole Relationships in Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 13 Intermolecular Forces and Boiling Points
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 14 A Simple Mercury Barometer
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 15 Vapor Pressure Lowering
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Standard Heat of Formation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 17 Determining Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 18 Changing Equilibrium Concentrations in a Reaction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 19 Swimming Pool Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Balancing OxidationndashReduction Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 21 Effect of Concentration on Cell Potential
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 22 Structural Isomers of Hexane
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 23 Boiling Points of Organic Families
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 25 The Production of Plutonium-239
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 26 The Phosphorus Cycle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Using Your Science Notebook
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Note-Taking Tips
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 1 Introduction to Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 11 The Stories of Two Chemicals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 12 Chemistry and Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 13 Scientific Methods
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 14 Scientific Research
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 2 Data Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 21 Units of Measurement
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 22 Scientific Notation and Dimensional Analysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 23 How reliable are measurements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 24 Representing Data
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 3 MattermdashProperties and Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 31 Properties of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 32 Changes in Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 33 Mixtures of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 34 Elements and Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 4 The Structure of the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 41 Early Theories of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 42 Subatomic Particles and the Nuclear Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 43 How Atoms Differ
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 44 Unstable Nuclei and Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 5 Electrons in Atoms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 51 Light and Quantized Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 52 Quantum Theory and the Atom
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 53 Electron Configurations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 6 The Periodic Table and Periodic Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 61 Development of the Modern Periodic Table
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 62 Classification of the Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 63 Periodic Trends
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 7 The Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 71 Properties of s-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 72 Properties of p-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 73 Properties of d-Block and f-Block Elements
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 8 Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 81 Forming Chemical Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 82 The Formation and Nature of Ionic Bonds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 83 Names and Formulas for Ionic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 84 Metallic Bonds and Properties of Metals
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 9 Covalent Bonding
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 91 The Covalent Bond
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 92 Naming Molecules
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 93 Molecular Structures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 94 Molecular Shape
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 95 Electronegativity and Polarity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 10 Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 101 Reactions and Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 102 Classifying Chemical Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 103 Reactions in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 11 The Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 111 Measuring Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 112 Mass and the Mole
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 113 Moles of Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 114 Empirical and Molecular Formulas
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 115 The Formula for a Hydrate
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 12 Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 121 What is stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 122 Stoichiometric Calculations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 123 Limiting Reactants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 124 Percent Yield
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 13 States of Matter
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 131 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 132 Forces of Attraction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 133 Liquids and Solids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 134 Phase Changes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 14 Gases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 141 The Gas Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 142 The Combined Gas Law and Avogadrorsquos Principle
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 143 The Ideal Gas Law
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 144 Gas Stoichiometry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 15 Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 151 What are solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 152 Solution Concentration
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 153 Colligative Properties of Solutions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 154 Heterogeneous Mixtures
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 16 Energy and Chemical Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 161 Energy
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 162 Heat in Chemical Reactions and Processes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 163 Thermochemical Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 164 Calculating Enthalpy Change
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 165 Reaction Spontaneity
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 17 Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 171 A Model for Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 172 Factors Affecting Reaction Rates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 173 Reaction Rate Laws
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 174 Instantaneous Reaction Rates and Reaction Mechanisms
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 18 Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 181 Equilibrium A State of Dynamic Balance
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 182 Factors Affecting Chemical Equilibrium
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 183 Using Equilibrium Constants
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 19 Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 191 Acids and Bases An Introduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 192 Strengths of Acids and Bases
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 193 What is pH
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 194 Neutralization
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 20 Redox Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 201 Oxidation and Reduction
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 202 Balancing Redox Equations
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 203 Half-Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 21 Electrochemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 211 Voltaic Cells
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 212 Types of Batteries
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 213 Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 22 Hydrocarbons
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 221 Alkanes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 222 Cyclic Alkanes and Alkane Properties
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 223 Alkenes and Alkynes
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 224 Isomers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 225 Aromatic Hydrocarbons and Petroleum
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  • Chapter 23 Substituted Hydrocarbons and Their Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 231 Functional Groups
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 232 Alcohols Ethers and Amines
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 233 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 234 Other Reactions of Organic Compounds
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Section 235 Polymers
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      • Chapter 24 The Chemistry of Life
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 241 Proteins
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 242 Carbohydrates
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 243 Lipids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 244 Nucleic Acids
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Section 245 Metabolism
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          • Chapter 25 Nuclear Chemistry
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Chapter Preview
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 251 Nuclear Radiation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 252 Radioactive Decay
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 253 Transmutation
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 254 Fission and Fusion of Atomic Nuclei
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Section 255 Applications and Effects of Nuclear Reactions
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            • Wrap-Up
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              • Chapter 26 Chemistry in the Environment
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                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 261 Earthrsquos Atmosphere
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 262 Earthrsquos Water
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 263 Earthrsquos Crust
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Section 264 Cycles in the Environment
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                • Wrap-Up
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